Alka-Seltzer® is an over-the-counter medicine used to treat acid indigestion and heartburn. The active pharmaceutical ingredients (API) in each Alka-Seltzer® tablet are aspirin (325 mg), citric acid (1.000 × 10³ mg), and sodium bicarbonate (1.916 × 10³ mg). For a single dose, two Alka-Seltzer® tablets are dissolved in 4.0 fluid ounces of water (1.0 fluid ounce = 29.57 mL), causing the following reaction:

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Alka-Seltzer® is an over-the-counter medicine used to treat acid indigestion and heartburn. The active
pharmaceutical ingredients (API) in each Alka-Seltzer® tablet are aspirin (325 mg), citric acid
(1.000 × 10° mg), and sodium bicarbonate (1.916 × 10° mg). For a single dose, two Alka-Seltzer®
tablets are dissolved in 4.0 fluid ounces of water (1.0 fluid ounce = 29.57 mL), causing the following
reaction:
C,H3O7(aq)+3NaHCO3(aq) → 3H2O(1) + 3CO2(g) + Na3C,H5O7(aq)
citric acid
sodium citrate
sodium
bicarbonate
(a) What volume of CO, gas (mL) at 25°C and 1 atm would be produced by a normal dose of
Alka-Seltzer®? Assume ideal-gas behavior and that the reaction goes to completion.
(b) You wake up feeling miserable before your material-and-energy-balances final exam, but you know
you can't miss it. You grab some Alka-Seltzer® and an 11-ounce bottle of water. You drink just
enough water to leave 4.0 fluid ounces in the bottle (you’ve had lots of practice with this). Then you
drop in the two tablets, screw the cap tightly onto the bottle, and rush out the door. Calculate the
pressure inside the bottle, assuming the temperature remains constant at 25°C and neglecting the
volume of the tablets.
(c) How reasonable are the assumptions of ideal-gas behavior in Parts (a) and (b)?
Transcribed Image Text:Alka-Seltzer® is an over-the-counter medicine used to treat acid indigestion and heartburn. The active pharmaceutical ingredients (API) in each Alka-Seltzer® tablet are aspirin (325 mg), citric acid (1.000 × 10° mg), and sodium bicarbonate (1.916 × 10° mg). For a single dose, two Alka-Seltzer® tablets are dissolved in 4.0 fluid ounces of water (1.0 fluid ounce = 29.57 mL), causing the following reaction: C,H3O7(aq)+3NaHCO3(aq) → 3H2O(1) + 3CO2(g) + Na3C,H5O7(aq) citric acid sodium citrate sodium bicarbonate (a) What volume of CO, gas (mL) at 25°C and 1 atm would be produced by a normal dose of Alka-Seltzer®? Assume ideal-gas behavior and that the reaction goes to completion. (b) You wake up feeling miserable before your material-and-energy-balances final exam, but you know you can't miss it. You grab some Alka-Seltzer® and an 11-ounce bottle of water. You drink just enough water to leave 4.0 fluid ounces in the bottle (you’ve had lots of practice with this). Then you drop in the two tablets, screw the cap tightly onto the bottle, and rush out the door. Calculate the pressure inside the bottle, assuming the temperature remains constant at 25°C and neglecting the volume of the tablets. (c) How reasonable are the assumptions of ideal-gas behavior in Parts (a) and (b)?
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