Ag+ forms two complexes with acetate, with the given overall formation constants. 1. Ag+ (aq) + CH3CO₂ (aq) Ag(CH₂ CO₂)(aq) K₁ = P₁ = 5.4 2. Ag+ (aq) + 2 CH3CO₂ (aq) Ag(CH₂ CO₂)2 (aq) B₂ = 4.4 Find the stepwise formation constant, K₂, for the reaction 3. Ag(CH,CO,)(aq) +CH,CO,(aq) = Ag(CH,CO,),(aq) K₂ =?

Chemistry & Chemical Reactivity
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Chapter18: Principles Of Chemical Reactivity: Entropy And Free Energy
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Ag+ forms two complexes with acetate, with the given overall formation constants.
1. Ag+ (aq) + CH₂CO (aq) ⇒
Ag(CH₂CO₂)(aq)
K₁ = P₁
2. Ag+ (aq) + 2 CH3CO₂ (aq)
Ag(CH₂CO₂)₂ (aq)
Find the stepwise formation constant, K₂, for the reaction
3. Ag(CH,CO,)(aq) + CH,CO,(aq) = Ag(CH,CO,) (aq) K₂ = ?
K₂=
=
0.8148
Ag+
B₂
1.12
= 5.4
=
You prepare 1.00 L of solution containing 1.00 × 10−4 mol AgCIO4 and 0.200 mol CH₂CO₂Na. Calculate the fraction of silver
in the form Ag*.
= 4.4
Transcribed Image Text:Ag+ forms two complexes with acetate, with the given overall formation constants. 1. Ag+ (aq) + CH₂CO (aq) ⇒ Ag(CH₂CO₂)(aq) K₁ = P₁ 2. Ag+ (aq) + 2 CH3CO₂ (aq) Ag(CH₂CO₂)₂ (aq) Find the stepwise formation constant, K₂, for the reaction 3. Ag(CH,CO,)(aq) + CH,CO,(aq) = Ag(CH,CO,) (aq) K₂ = ? K₂= = 0.8148 Ag+ B₂ 1.12 = 5.4 = You prepare 1.00 L of solution containing 1.00 × 10−4 mol AgCIO4 and 0.200 mol CH₂CO₂Na. Calculate the fraction of silver in the form Ag*. = 4.4
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