Additional Exercise 19.111 An Ag/AgCl electrode dipping into 1.00 M HCI has a standard reduction potential of +0.2223 v. The half-reaction is AgC(s) + e= Ag(s) +CI(aq) A second Ag/AgCl electrode is dipped into a solution containing Cl" at an unknown concentration. The cell generates a potential of 0.0522 V, with the electrode in the solution of unknown concentration having a negative charge. What is the molar concentration of CI" in the unknown solution? [Cr] = the tolerance is +/-2% Click if you would like to Show Work for this question: Open Show Work

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Additional Exercise 19.111
An Ag/AgCl electrode dipping into 1.00 M HCI has a standard reduction potential of +0.2223 V.
The half-reaction is
AgCI(s) + e
Ag(s) +Cl"(aq)
A second Ag/AgCl electrode is dipped into a solution containing Cl" at an unknown concentration.
The cell generates a potential of 0.0522 V, with the electrode in the solution of unknown concentration having a negative charge.
What is the molar concentration of CI in the unknown solution?
[Cr] =
%D
the tolerance is +/-2%
Click if you would like to Show Work for this question: Open Show Work
Transcribed Image Text:Additional Exercise 19.111 An Ag/AgCl electrode dipping into 1.00 M HCI has a standard reduction potential of +0.2223 V. The half-reaction is AgCI(s) + e Ag(s) +Cl"(aq) A second Ag/AgCl electrode is dipped into a solution containing Cl" at an unknown concentration. The cell generates a potential of 0.0522 V, with the electrode in the solution of unknown concentration having a negative charge. What is the molar concentration of CI in the unknown solution? [Cr] = %D the tolerance is +/-2% Click if you would like to Show Work for this question: Open Show Work
Multi-Concept Problem 19.117
At 25 °C, a galvanic cell was set up having the following half-reactions.
Fe2+(aq) + 2eS Fe(s), E°Fe2+
Cu2+(aq) + 2e S Cu(s), E°cu2+
= -0.447 V
= +0.3419 V
The copper half-cell contained 100 mL of 3.85 M CuSO4. The iron half-cell contained 31.6 mL of 0.312 M FeSO4. To the iron half-cell was added 43.5 mL of 0.662 M NaOH solution. The mixtu
was stirred and the cell potential was measured to be 1.175 V. Calculate the value of Ksp for Fe(OH),.
Ksp
the tolerance is +/-2%
Click if you would like to Show Work for this question: Open Show Work
Transcribed Image Text:Multi-Concept Problem 19.117 At 25 °C, a galvanic cell was set up having the following half-reactions. Fe2+(aq) + 2eS Fe(s), E°Fe2+ Cu2+(aq) + 2e S Cu(s), E°cu2+ = -0.447 V = +0.3419 V The copper half-cell contained 100 mL of 3.85 M CuSO4. The iron half-cell contained 31.6 mL of 0.312 M FeSO4. To the iron half-cell was added 43.5 mL of 0.662 M NaOH solution. The mixtu was stirred and the cell potential was measured to be 1.175 V. Calculate the value of Ksp for Fe(OH),. Ksp the tolerance is +/-2% Click if you would like to Show Work for this question: Open Show Work
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