Addition of 1-bromobut-2-ene to magnesium metal in dry ether results in formation of aGrignard reagent. Addition of water to this Grignard reagent gives a mixture of but-1-eneand but-2-ene (cis and trans). When the Grignard reagent is made using 3-bromobut-1-ene,addition of water produces exactly the same mixture of products in the same ratios.Explain this curious result.
Reactions of Ethers
Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.
Epoxides
Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.
Williamson Ether Synthesis
An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.
Addition of 1-bromobut-2-ene to magnesium metal in dry ether results in formation of a
Grignard reagent. Addition of water to this Grignard reagent gives a mixture of but-1-ene
and but-2-ene (cis and trans). When the Grignard reagent is made using 3-bromobut-1-ene,
addition of water produces exactly the same mixture of products in the same ratios.
Explain this curious result.
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