Activity: Research and describe the properties for each crystals. Use the following as bases of property comparison. Strength or hardness Melting point Electrical conductibility

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please help me with my he. Please answer letter a numbers 1-3 completely. Please refer on the text below as well as the picture included. Note: The picture inlcuded is the first page.

 


TYPES OF SOLIDS AND THEIR PROPERTIES

  • Solids can be categorized as crystalline and amorphous. The difference in properties of these two groups of solid arises from the presence or absence of long range order of arrangement of the particles in the solid.

 

Properties

Crystalline Solid

Amorphous solid

Arrangement of particles

Arranged in fixed geometric pattern or lattices.

Have random orientation of particles

Behavior when heated

Attractive forces are broken by same amount of energy, thus, becomes liquid at a specific temperature.

Softens when gradually heated, they tend to melt over a wide range of temperature.

 

FACTS:

  1. More than 90% of naturally occurring and artificially prepared solids are crystalline.
  2. The repetition of structural units of substance over long atomic distances is referred to as long-range order.
  3. The repeating units of crystalline solids are called lattices.
  4. X-ray diffraction is a technique used to determine the atomic and molecular structure of a crystal, wherein atoms cause a beams of incident X-rays to diffract into many specific directions.

 

FOUR TYPES OF CRYSTALS (SOLID)

  1. Metallic crystals. Made of atoms that readily lose electrons to form positive ions (cations) but no atom in the crystal would readily gain electrons. The metal atoms gives up their electrons to the whole crystal, creating a structure made up of an orderly arrangement of cations surrounded by delocalized electrons that move around the crystal. The crystal is held together by electrostatic interactions between the cations and delocalized electron. These interactions are called “metallic bonds” and the model is termed as “sea of electrons model”.
  2. Ionic crystals. Made of ions (cations and anions) which form strong electrostatic interactions that hold the crystal lattice together. The electrostatic attractions are numerous and extend throughout the crystal since each ion is surrounded by several ions of opposite charge, making ionic crystals hard and of high melting points.
  3. Molecular crystals. Made up of atoms, such as noble gases, or molecules such as sugar, iodine and naphthalene. The atoms or molecules are held together by a mix hydrogen bonding/dipole-dipole and dispersion forces, and these are the attractive forces that are broken when crystal melts.
  4. Covalent network crystals. Made of atoms in which atom is covalently bonded to its nearest neighbors. The atoms can be made of one type of atom or made ofcan be made of different atoms. There are no individual molecules and the entire crystal mat be considered one very large molecule. The valence electrons of the atoms in the crystal are all used to form covalent bonds because there are no delocalized electrons, covalent network solids do not conduct electricity. Covalent bonds are the only type of attractive bond between atoms in network solid.

 

Type of Solid

Form of Unit Particle

Forces Between Particle

Properties

Example

Molecular

Atoms/molecules

London Dispersion

 

Dipole-dipole forces

 

Hydrogen Bonds

 

Argon, Methane

Covalent Network

Atoms in a network of covalent bonds

Covalent Bonds

 

Diamond, quarts

Ionic

Positive and negative ion

Electrostatic Attraction/Ionic Bonds

 

Typical salts, Sodium Chloride, Potassium Chloride, Calcium Nitrate

Metallic

Atoms

Metallic Bonds

 

All  metallic elments.

 

Activity:

  1. Research and describe the properties for each crystals. Use the following as bases of property comparison.
  2. Strength or hardness
  3. Melting point
  4. Electrical conductibility
  5. Heat conductibility
  6. Brittleness
PROPERTIES OF LIQUID AND INTERMOLECULAR FORCES
1. Surface Tension. It is the measure of elastic force in the surface of a liquid. It is the
amount of energy required to stretch or increase the surface of a liquid by a unit
area. Intermolecular forces affect the magnitude of surface tension. Molecules
within a liquid are pulled in all direction by intermolecular forces.
SURFACE TENSION
Needle
Needle
Water
degastly
2. Capillary Action. It is the tendency of a liquid to rise in narrow tubes or to be drawn
into small openings such as those between grains of rock. It is also known as
capillarity which is a result of intermolecular attraction between the liquid and solid
materials. There are two types of forces involved in capillary action:
Cohesion. Intermolecular attraction between like molecules (eg: liquid
molecules).
b. Adhesion. Attraction between unlike molecules (eg: water and particles of
the glass tube in which it passes)
a.
Concave
meniscus
Convex
meniscus
H2O
Hg
Adhesion
Cohesion
3. Viscosity. It is a measure of fluid's resistance to flow. The greater the viscosity, the
slower the liquid flows.
4. Vapor pressure. It is a measure of the tendency of a material to change into the
gaseous or vapour state, and it increases with temperature. The temperature at
which the vapour pressure at the surface of a liquid becomes equal to
the pressure exerted by the surroundings is called the boiling point of the liquid. So
as the temperature increases, the vapour pressure of water also increases. When
temperature is high, more molecules have enough energy to escape from the liquid.
On the other hand, at lower temperature, fewer molecules have sufficient energy to
escape from the liquid.
5. Molar Heat of vaporization. It is the energy required to vaporize 1 mol of a liquid at
a given temperature. The heat of vaporization may be considered a measure of
strength of intermolecular forces in a liquid. If intermolecular forces are strong, it
takes a lot of energy to free the molecules from the liquid phase and the heat of
vaporization will be high.
Transcribed Image Text:PROPERTIES OF LIQUID AND INTERMOLECULAR FORCES 1. Surface Tension. It is the measure of elastic force in the surface of a liquid. It is the amount of energy required to stretch or increase the surface of a liquid by a unit area. Intermolecular forces affect the magnitude of surface tension. Molecules within a liquid are pulled in all direction by intermolecular forces. SURFACE TENSION Needle Needle Water degastly 2. Capillary Action. It is the tendency of a liquid to rise in narrow tubes or to be drawn into small openings such as those between grains of rock. It is also known as capillarity which is a result of intermolecular attraction between the liquid and solid materials. There are two types of forces involved in capillary action: Cohesion. Intermolecular attraction between like molecules (eg: liquid molecules). b. Adhesion. Attraction between unlike molecules (eg: water and particles of the glass tube in which it passes) a. Concave meniscus Convex meniscus H2O Hg Adhesion Cohesion 3. Viscosity. It is a measure of fluid's resistance to flow. The greater the viscosity, the slower the liquid flows. 4. Vapor pressure. It is a measure of the tendency of a material to change into the gaseous or vapour state, and it increases with temperature. The temperature at which the vapour pressure at the surface of a liquid becomes equal to the pressure exerted by the surroundings is called the boiling point of the liquid. So as the temperature increases, the vapour pressure of water also increases. When temperature is high, more molecules have enough energy to escape from the liquid. On the other hand, at lower temperature, fewer molecules have sufficient energy to escape from the liquid. 5. Molar Heat of vaporization. It is the energy required to vaporize 1 mol of a liquid at a given temperature. The heat of vaporization may be considered a measure of strength of intermolecular forces in a liquid. If intermolecular forces are strong, it takes a lot of energy to free the molecules from the liquid phase and the heat of vaporization will be high.
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