Acetate can form ester with alcohols tike methanol, ethanol, isopropanol, n-butanol, etc. One of such acetate esters has a formula of CsHo. Its H-NMR is shown below. What's the structure of this acetate ester? Assign NMR peaks. Show your work: include an explanation for the different chemical shifts. 6H 3H 1H PPM

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You're considering synthesizing 1-octanol from acetate in a microorganism. Octanoate is made
Problems
1-octanol is a petroleum lubricating oil and a potential biofuel with diesel-ike properties. 1-octanol
Can be made from reducinr octanoate with two equivalents of NADPH.
• 2NADP
2NADPH
durina onsidering synthesizing 1 Octanol from acetate in a microorgganism. Octanoate is made
atty acid synthesis, in a waN Fimilar to palmitate except with early termination.
acetate
ATP
X ATP
X ADP
ADP
Fs
Fobj
Acetyl-CoA
1-octanol
octanoate
Oxaloacetate F
Y NADP
2NADP
citrate
Y NADPH
2NADPH
ADP
2.5 ADP
2.5 ATP
F
* ATP
Fo
3NADP
NADP
NADPH
3NADPH
A. Acetate can form ester with alcohols like methanol, ethanol, isopropanol, n-butanol, etc. One c
such acetate esters has a formula of CSH10O2. Its 'H-NMR is shown below. Whats the structur
of this acetate ester? Assign NMR peaks. Show your work: include an explanation for the
different chemical shifts.
6H
Transcribed Image Text:You're considering synthesizing 1-octanol from acetate in a microorganism. Octanoate is made Problems 1-octanol is a petroleum lubricating oil and a potential biofuel with diesel-ike properties. 1-octanol Can be made from reducinr octanoate with two equivalents of NADPH. • 2NADP 2NADPH durina onsidering synthesizing 1 Octanol from acetate in a microorgganism. Octanoate is made atty acid synthesis, in a waN Fimilar to palmitate except with early termination. acetate ATP X ATP X ADP ADP Fs Fobj Acetyl-CoA 1-octanol octanoate Oxaloacetate F Y NADP 2NADP citrate Y NADPH 2NADPH ADP 2.5 ADP 2.5 ATP F * ATP Fo 3NADP NADP NADPH 3NADPH A. Acetate can form ester with alcohols like methanol, ethanol, isopropanol, n-butanol, etc. One c such acetate esters has a formula of CSH10O2. Its 'H-NMR is shown below. Whats the structur of this acetate ester? Assign NMR peaks. Show your work: include an explanation for the different chemical shifts. 6H
ANADP
3NADPH
NADP
NADPH
A.
Acetate can form ester with alcohols like methanol, ethanol, isopropanol, n-butanol, etc. One of
such acetate esters has a formula of CsHjo02. Its 'H-NMR is shown below. What's the structure
of this acetate ester? Assign NMR peaks. Show your work: Include an explanation for the
different chemical shifts.
6H
3H
1H
6.
5
4.
PPM
Transcribed Image Text:ANADP 3NADPH NADP NADPH A. Acetate can form ester with alcohols like methanol, ethanol, isopropanol, n-butanol, etc. One of such acetate esters has a formula of CsHjo02. Its 'H-NMR is shown below. What's the structure of this acetate ester? Assign NMR peaks. Show your work: Include an explanation for the different chemical shifts. 6H 3H 1H 6. 5 4. PPM
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