A. What is the order of the reaction with respect to acetone? B. What is the order of the reaction with respect to bromine? C. What is the order of the reaction with respect to acid? D. Determine the average rate constant for the 5 reaction mixtures. E. Write the complete rate law for the reaction based on the experimental data given.

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Chapter1: Chemical Foundations
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1. The bromination of acetone is acid-catalyzed:
CH3COCH3 + Br2 → CH3COCH2BR + H* + Br
The rate of disappearance of bromine was measured for several different
concentrations of acetone, bromine and H+ ions at a certain temperature:
Rate of disappearance
[CH3COCH3]
[Br2]
[H*]
0.050
of Br2 (M/s)
(a)
(b)
(c)
(d)
(e)
5.7 x 105
5.7 x 105
1.2 x 104
3.1 x 104
7.6 x 105
0.30
0.050
0.30
0.10
0.050
0.30
0.050
0.10
0.40
0.050
0.20
0.40
0.050
0.050
A. What is the order of the reaction with respect to acetone?
B. What is the order of the reaction with respect to bromine?
C. What is the order of the reaction with respect to acid?
D. Determine the average rate constant for the 5 reaction mixtures.
E. Write the complete rate law for the reaction based on the experimental data given.
Transcribed Image Text:1. The bromination of acetone is acid-catalyzed: CH3COCH3 + Br2 → CH3COCH2BR + H* + Br The rate of disappearance of bromine was measured for several different concentrations of acetone, bromine and H+ ions at a certain temperature: Rate of disappearance [CH3COCH3] [Br2] [H*] 0.050 of Br2 (M/s) (a) (b) (c) (d) (e) 5.7 x 105 5.7 x 105 1.2 x 104 3.1 x 104 7.6 x 105 0.30 0.050 0.30 0.10 0.050 0.30 0.050 0.10 0.40 0.050 0.20 0.40 0.050 0.050 A. What is the order of the reaction with respect to acetone? B. What is the order of the reaction with respect to bromine? C. What is the order of the reaction with respect to acid? D. Determine the average rate constant for the 5 reaction mixtures. E. Write the complete rate law for the reaction based on the experimental data given.
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