a. The mechanism involves carbocation intermediates. b. The mechanism has two steps. c. The reaction rate increases with better leaving groups. d. The reaction rate increases when the solvent is changed from CH₂OH to (CH₂)₂SO. e. The reaction rate depends on the concentration of the alkyl halide only. f. The mechanism is concerted. g. The reaction of CH3CH₂Br with NaOH occurs by this mechanism. h. Racemization at a stereogenic center occurs. i. Tertiary (3°) alkyl halides react faster than 2° or 1° alkyl halides. j. The reaction follows a second-order rate equation.
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
For which reaction mechanisms - Sn1,Sn2, E1, or E2- are each of the following statements true? A statement may be true for one or more mechanisms.
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