a. The coordination compound potassium hexafluoronickelate (K2[NİF6]) has been synthesized and characterized. It is red in color. Use this information to calculate an approximate value of the octahedral field splitting energy for K2[NİF6]. Report you answer in units of kJ/mol. b. Predict the expected magnetic characteristics of potassium hexafluoronickelate (K2[NIF6]). Explain your answer.

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Part a,b
the laboratory we examined a few nickel coordination compounds, however, we were
only able to scratch the surface with regards to the coordination chemistry of nickel. Consider these
other nickel coordination compounds.
a. The coordination compound potassium hexafluoronickelate (K2[NİF6]) has been synthesized
and characterized. It is red in color. Use this information to calculate an approximate value
of the octahedral field splitting energy for K2[NİF6]. Report you answer in units of kJ/mol.
b. Predict the expected magnetic characteristics of potassium hexafluoronickelate (K2[NIF6]).
Explain your answer.
c. The nickel coordination compound bis(P,P-dialkylphosphinic-N-ethylamidato-N,S) nickel
sounds complicated, but it's not too bad. The ligand P,P-dialkylphosphinic-N-ethylamidato-
N,S (abbreviated SPR2N) is a bidentate ligand that forms coordinate covalent bonds to a
Lewis acidic metal through its sulfur and nitrogen Lewis basic atoms as shown below:
R
P,P-dialkylphosphinic-N-ethylamidato-N,S
R
Ligand abbreviation: SPR,N-
H2C
R = C(CH3)3
CH3
Ni(SPR2N)2 is diamagnetic in the solid state. However, when Ni(SPR,N)2 is dissolved in
solution, it is paramagnetic. Given that the coordinate covalent bonds remain intact in both
the solid state and dissolved forms, provide an explanation for what may be occurring that
causes the change in magnetic properties.
Transcribed Image Text:the laboratory we examined a few nickel coordination compounds, however, we were only able to scratch the surface with regards to the coordination chemistry of nickel. Consider these other nickel coordination compounds. a. The coordination compound potassium hexafluoronickelate (K2[NİF6]) has been synthesized and characterized. It is red in color. Use this information to calculate an approximate value of the octahedral field splitting energy for K2[NİF6]. Report you answer in units of kJ/mol. b. Predict the expected magnetic characteristics of potassium hexafluoronickelate (K2[NIF6]). Explain your answer. c. The nickel coordination compound bis(P,P-dialkylphosphinic-N-ethylamidato-N,S) nickel sounds complicated, but it's not too bad. The ligand P,P-dialkylphosphinic-N-ethylamidato- N,S (abbreviated SPR2N) is a bidentate ligand that forms coordinate covalent bonds to a Lewis acidic metal through its sulfur and nitrogen Lewis basic atoms as shown below: R P,P-dialkylphosphinic-N-ethylamidato-N,S R Ligand abbreviation: SPR,N- H2C R = C(CH3)3 CH3 Ni(SPR2N)2 is diamagnetic in the solid state. However, when Ni(SPR,N)2 is dissolved in solution, it is paramagnetic. Given that the coordinate covalent bonds remain intact in both the solid state and dissolved forms, provide an explanation for what may be occurring that causes the change in magnetic properties.
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