a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the Tables link on the drop-down that appears. Include algebraic sign and units. b. Is the reaction exothermic or endothermie? c. Is the reaction likely to proceed spontaneously in the direction written?

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For the reaction below:
CH₂-H
CH₂
OH
-
H-OH
a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the
References button and then click the Tables link on the drop-down that appears. Include algebraic sign and units.
b. Is the reaction exothermic or endothermie?
c. Is the reaction likely to proceed spontaneously in the direction written?
Transcribed Image Text:For the reaction below: CH₂-H CH₂ OH - H-OH a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the Tables link on the drop-down that appears. Include algebraic sign and units. b. Is the reaction exothermic or endothermie? c. Is the reaction likely to proceed spontaneously in the direction written?
Bond Dissociation Energies, Dº 298, for X-Y
kJ/mol (kcal/mol)
X | Y=
H
F
cl
Br
I
OH
NH₂
356 (85)
439 (105)
452 (108) 356 (85)
238 (57) 385 (92)
CH3-
CH3CH2-
293 (70)
285 (68)
423 (101)
444 (106)
335 (80)
228 (53)
380 (91)
356 (85)
(CH3)2CH-
409 (98)
448 (107)
339 (81)
274 (65)
226 (54)
385 (92)
(CH3)3C-
404 (97)
331 (79)
263 (63)
213 (51)
380 (91)
CH₂=CHCH₂-
362 (86.5)
289 (69)
230 (55)
172 (41)
CH₂
376 (90)
301 (72) 243 (58)
201 (48)
CH₂=CH-
465 (111)
368 (87)
259 (62)
473 (113) 527 (126) 402 (96) 337 (80.5) 274 (65) 464 (111) 427 (102)
CH30-
436 (104)
H-
435 (104) 569 (136) 431 (103) 368 (88)
Most data from CRC handbook of Chemistry and Physics, 85th ed., D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-65.
Uncertainties range from less than 1 kJ/mol to ca. 20 kJ/mol (5 kcal/mol) and are listed in the CRC handbook.
CN
510 (122)
336 (80)
536 (128)
377 (90)
333 (80)
297 (71) 498 (119) 449 (107) 439 (105) 423 (101) 543 (130)
CH3
377 (90)
368 (88)
351(84)
339 (81)
305 (73)
332 (79)
406 (97)
CH3CH₂-
368 (88)
Transcribed Image Text:Bond Dissociation Energies, Dº 298, for X-Y kJ/mol (kcal/mol) X | Y= H F cl Br I OH NH₂ 356 (85) 439 (105) 452 (108) 356 (85) 238 (57) 385 (92) CH3- CH3CH2- 293 (70) 285 (68) 423 (101) 444 (106) 335 (80) 228 (53) 380 (91) 356 (85) (CH3)2CH- 409 (98) 448 (107) 339 (81) 274 (65) 226 (54) 385 (92) (CH3)3C- 404 (97) 331 (79) 263 (63) 213 (51) 380 (91) CH₂=CHCH₂- 362 (86.5) 289 (69) 230 (55) 172 (41) CH₂ 376 (90) 301 (72) 243 (58) 201 (48) CH₂=CH- 465 (111) 368 (87) 259 (62) 473 (113) 527 (126) 402 (96) 337 (80.5) 274 (65) 464 (111) 427 (102) CH30- 436 (104) H- 435 (104) 569 (136) 431 (103) 368 (88) Most data from CRC handbook of Chemistry and Physics, 85th ed., D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-65. Uncertainties range from less than 1 kJ/mol to ca. 20 kJ/mol (5 kcal/mol) and are listed in the CRC handbook. CN 510 (122) 336 (80) 536 (128) 377 (90) 333 (80) 297 (71) 498 (119) 449 (107) 439 (105) 423 (101) 543 (130) CH3 377 (90) 368 (88) 351(84) 339 (81) 305 (73) 332 (79) 406 (97) CH3CH₂- 368 (88)
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