or the reaction below: CH3CH, CH;CH; Cl- H-a Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the ables link on the drop-down that appears. Include algebraic sign and units. Is the reaction exothermic or endothermic?| Is the reaction likely to proceed spontaneously in the direction written?

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the Tables link on the drop-down that appears. Include algebraic sign and units.

b. Is the reaction exothermic or endothermic? 

c. Is the reaction likely to proceed spontaneously in the direction written? 

 

Reference the graph when needed. Please and thank you.

For the reaction below:
CH;CH3
Cl-
CH;CH2
H-a
a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the
Tables link on the drop-down that appears. Include algebraic sign and units.
b. Is the reaction exothermic or endothermic?|
c. Is the reaction likely to proceed spontaneously in the direction written?
Transcribed Image Text:For the reaction below: CH;CH3 Cl- CH;CH2 H-a a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the Tables link on the drop-down that appears. Include algebraic sign and units. b. Is the reaction exothermic or endothermic?| c. Is the reaction likely to proceed spontaneously in the direction written?
Bond Dissociation Energies
Bond Dissociation Energies, D°298, for X-Y
ka/mol (kcal/mol)
XIY-
H
a
Br
он
NH3
CH3
CH;CH
CN
439 (105) 452 (108) 356 (85) 293 (70) 238 (57) 385 (92) 356 (85) 377 (90) 368 (88) s10 (122)
423 (101) 444 (106) 335 (80) 285 (68) 228 (53) 380 (91) 356 (85) 368 (88)
409 (98) 448 (107) 339 (81) 274 (65) 226 (54) 385 (92)
CHy
CH,CH-
336 (80)
(CH3;CH-
351(84)
331 (79) 263 (63) 213 (51) 380 (91)
289 (69) 230 (55) 172 (41)
(CHahC-
404 (97)
339 (81)
CH-CHCH- 362 (86.5)
305 (73)
CH
376 (90)
301 (72) 243 (58) 201 (48)
332 (79)
CH-CH-
465 (111)
368 (87)
259 (62)
406 (97)
536 (128)
473 (113) 527 (126) 402 (96) 337 (80.5) 274 (65) 464 (111) 427 (102)
377 (90)
CH30-
436 (104)
333 (80)
| 435 (104) 569 (136) 431 (103) 368 (88) 297 (71)| 498 (119) 449 (107) 439 (105) 423 (101) 543 (130)
H-
Most data from CRC handhook of Chemistry and Physics, 85th ed, D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-65.
Uncertainties range from less than I kimol to ca. 20 klimol (5 kcal'mol) and are listed in the CRC handbook.
Additional Bond Dissociation Energies
/mol (kcal/mol)
Bond
Bond
D°2
Вond
D°398
Bond
HC#CH 965 (231) (CH3)hSi-H 378 (90)
F-F
159 (38) Bио-ови 159 (38)
498 (119) HC=C-H 556 (133) (CH),Ge-H 340 (81)
732 (175) C3C-CI
CHCI 243 (58)
Br-Br 192 (46)
151 (36) H;C-0 732 (175) CH,CO-H 374 (89)
но он 213 (51) Н,с-CH; |728 (174)
0-0
nBuşSn-H 308 (74)
OC-O
392 (94)
I-I
CH,S-H 365 (87)
data from CRC handbook of Chemistry and Physics, 85th ed., D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-52.
Uncertainties range from less than I kl/mol to ca. 20 kl/mol (5 kcal/mol) and are listed in the CRC handbook.
Transcribed Image Text:Bond Dissociation Energies Bond Dissociation Energies, D°298, for X-Y ka/mol (kcal/mol) XIY- H a Br он NH3 CH3 CH;CH CN 439 (105) 452 (108) 356 (85) 293 (70) 238 (57) 385 (92) 356 (85) 377 (90) 368 (88) s10 (122) 423 (101) 444 (106) 335 (80) 285 (68) 228 (53) 380 (91) 356 (85) 368 (88) 409 (98) 448 (107) 339 (81) 274 (65) 226 (54) 385 (92) CHy CH,CH- 336 (80) (CH3;CH- 351(84) 331 (79) 263 (63) 213 (51) 380 (91) 289 (69) 230 (55) 172 (41) (CHahC- 404 (97) 339 (81) CH-CHCH- 362 (86.5) 305 (73) CH 376 (90) 301 (72) 243 (58) 201 (48) 332 (79) CH-CH- 465 (111) 368 (87) 259 (62) 406 (97) 536 (128) 473 (113) 527 (126) 402 (96) 337 (80.5) 274 (65) 464 (111) 427 (102) 377 (90) CH30- 436 (104) 333 (80) | 435 (104) 569 (136) 431 (103) 368 (88) 297 (71)| 498 (119) 449 (107) 439 (105) 423 (101) 543 (130) H- Most data from CRC handhook of Chemistry and Physics, 85th ed, D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-65. Uncertainties range from less than I kimol to ca. 20 klimol (5 kcal'mol) and are listed in the CRC handbook. Additional Bond Dissociation Energies /mol (kcal/mol) Bond Bond D°2 Вond D°398 Bond HC#CH 965 (231) (CH3)hSi-H 378 (90) F-F 159 (38) Bио-ови 159 (38) 498 (119) HC=C-H 556 (133) (CH),Ge-H 340 (81) 732 (175) C3C-CI CHCI 243 (58) Br-Br 192 (46) 151 (36) H;C-0 732 (175) CH,CO-H 374 (89) но он 213 (51) Н,с-CH; |728 (174) 0-0 nBuşSn-H 308 (74) OC-O 392 (94) I-I CH,S-H 365 (87) data from CRC handbook of Chemistry and Physics, 85th ed., D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-52. Uncertainties range from less than I kl/mol to ca. 20 kl/mol (5 kcal/mol) and are listed in the CRC handbook.
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