or the reaction below: CH3CH, CH;CH; Cl- H-a Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the ables link on the drop-down that appears. Include algebraic sign and units. Is the reaction exothermic or endothermic?| Is the reaction likely to proceed spontaneously in the direction written?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question

a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the Tables link on the drop-down that appears. Include algebraic sign and units.

b. Is the reaction exothermic or endothermic? 

c. Is the reaction likely to proceed spontaneously in the direction written? 

 

Reference the graph when needed. Please and thank you.

For the reaction below:
CH;CH3
Cl-
CH;CH2
H-a
a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the
Tables link on the drop-down that appears. Include algebraic sign and units.
b. Is the reaction exothermic or endothermic?|
c. Is the reaction likely to proceed spontaneously in the direction written?
Transcribed Image Text:For the reaction below: CH;CH3 Cl- CH;CH2 H-a a. Estimate the gas phase enthalpy change using bond dissociation enthalpies from the OWL Table Reference, not data from your text. Click the References button and then click the Tables link on the drop-down that appears. Include algebraic sign and units. b. Is the reaction exothermic or endothermic?| c. Is the reaction likely to proceed spontaneously in the direction written?
Bond Dissociation Energies
Bond Dissociation Energies, D°298, for X-Y
ka/mol (kcal/mol)
XIY-
H
a
Br
он
NH3
CH3
CH;CH
CN
439 (105) 452 (108) 356 (85) 293 (70) 238 (57) 385 (92) 356 (85) 377 (90) 368 (88) s10 (122)
423 (101) 444 (106) 335 (80) 285 (68) 228 (53) 380 (91) 356 (85) 368 (88)
409 (98) 448 (107) 339 (81) 274 (65) 226 (54) 385 (92)
CHy
CH,CH-
336 (80)
(CH3;CH-
351(84)
331 (79) 263 (63) 213 (51) 380 (91)
289 (69) 230 (55) 172 (41)
(CHahC-
404 (97)
339 (81)
CH-CHCH- 362 (86.5)
305 (73)
CH
376 (90)
301 (72) 243 (58) 201 (48)
332 (79)
CH-CH-
465 (111)
368 (87)
259 (62)
406 (97)
536 (128)
473 (113) 527 (126) 402 (96) 337 (80.5) 274 (65) 464 (111) 427 (102)
377 (90)
CH30-
436 (104)
333 (80)
| 435 (104) 569 (136) 431 (103) 368 (88) 297 (71)| 498 (119) 449 (107) 439 (105) 423 (101) 543 (130)
H-
Most data from CRC handhook of Chemistry and Physics, 85th ed, D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-65.
Uncertainties range from less than I kimol to ca. 20 klimol (5 kcal'mol) and are listed in the CRC handbook.
Additional Bond Dissociation Energies
/mol (kcal/mol)
Bond
Bond
D°2
Вond
D°398
Bond
HC#CH 965 (231) (CH3)hSi-H 378 (90)
F-F
159 (38) Bио-ови 159 (38)
498 (119) HC=C-H 556 (133) (CH),Ge-H 340 (81)
732 (175) C3C-CI
CHCI 243 (58)
Br-Br 192 (46)
151 (36) H;C-0 732 (175) CH,CO-H 374 (89)
но он 213 (51) Н,с-CH; |728 (174)
0-0
nBuşSn-H 308 (74)
OC-O
392 (94)
I-I
CH,S-H 365 (87)
data from CRC handbook of Chemistry and Physics, 85th ed., D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-52.
Uncertainties range from less than I kl/mol to ca. 20 kl/mol (5 kcal/mol) and are listed in the CRC handbook.
Transcribed Image Text:Bond Dissociation Energies Bond Dissociation Energies, D°298, for X-Y ka/mol (kcal/mol) XIY- H a Br он NH3 CH3 CH;CH CN 439 (105) 452 (108) 356 (85) 293 (70) 238 (57) 385 (92) 356 (85) 377 (90) 368 (88) s10 (122) 423 (101) 444 (106) 335 (80) 285 (68) 228 (53) 380 (91) 356 (85) 368 (88) 409 (98) 448 (107) 339 (81) 274 (65) 226 (54) 385 (92) CHy CH,CH- 336 (80) (CH3;CH- 351(84) 331 (79) 263 (63) 213 (51) 380 (91) 289 (69) 230 (55) 172 (41) (CHahC- 404 (97) 339 (81) CH-CHCH- 362 (86.5) 305 (73) CH 376 (90) 301 (72) 243 (58) 201 (48) 332 (79) CH-CH- 465 (111) 368 (87) 259 (62) 406 (97) 536 (128) 473 (113) 527 (126) 402 (96) 337 (80.5) 274 (65) 464 (111) 427 (102) 377 (90) CH30- 436 (104) 333 (80) | 435 (104) 569 (136) 431 (103) 368 (88) 297 (71)| 498 (119) 449 (107) 439 (105) 423 (101) 543 (130) H- Most data from CRC handhook of Chemistry and Physics, 85th ed, D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-65. Uncertainties range from less than I kimol to ca. 20 klimol (5 kcal'mol) and are listed in the CRC handbook. Additional Bond Dissociation Energies /mol (kcal/mol) Bond Bond D°2 Вond D°398 Bond HC#CH 965 (231) (CH3)hSi-H 378 (90) F-F 159 (38) Bио-ови 159 (38) 498 (119) HC=C-H 556 (133) (CH),Ge-H 340 (81) 732 (175) C3C-CI CHCI 243 (58) Br-Br 192 (46) 151 (36) H;C-0 732 (175) CH,CO-H 374 (89) но он 213 (51) Н,с-CH; |728 (174) 0-0 nBuşSn-H 308 (74) OC-O 392 (94) I-I CH,S-H 365 (87) data from CRC handbook of Chemistry and Physics, 85th ed., D. R. Lide, ed., CRC press, Boca Raton, FL, 2004, p 9-52. Uncertainties range from less than I kl/mol to ca. 20 kl/mol (5 kcal/mol) and are listed in the CRC handbook.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Thermochemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY