(a) Which of the following reactant concentrations could you use for experiment 3 in order to determine the rate law, assuming that the rate law is of the form, Ratek [A] []? Choose all correct possibilities. O [A] 0.2 and [0] -1.0 [A] 0.4 and [8] - 1.0 [A] 0.8 and [0]=0.5 [A] 0.6 and [8] -0.5 [A] 0.2 and [0] = 1.5 [A] 0.4 and [0] -0.5 0.4 and (0) - 1.5 1.0 and [0] -0.5 O [A] O[A] (b) For a reaction of the form, A+B+C --> Products, the following observations are made: doubling the concentration of A increases the rate by a factor of 8. doubling the concentration of 8 has no effect on the rate, and doubling the concentration of C increases the rate by a factor of 2. Select the correct rate law for this reaction from the choices below. O Rate-k[A][B][C] O Rate-[A][C] O Rate - K[A]²[C] O Rate = K[A][C]² O Rate = K[A]²[C]² O Rate=K[A] [C] O Rate-k[A][C]³ (c) By what factor will the rate of the reaction described in part (b) above change if the concentrations of A, B, and C are all halved (reduced by a factor of 2)? The rate will be the original rate multiplied by a factor of
(a) Which of the following reactant concentrations could you use for experiment 3 in order to determine the rate law, assuming that the rate law is of the form, Ratek [A] []? Choose all correct possibilities. O [A] 0.2 and [0] -1.0 [A] 0.4 and [8] - 1.0 [A] 0.8 and [0]=0.5 [A] 0.6 and [8] -0.5 [A] 0.2 and [0] = 1.5 [A] 0.4 and [0] -0.5 0.4 and (0) - 1.5 1.0 and [0] -0.5 O [A] O[A] (b) For a reaction of the form, A+B+C --> Products, the following observations are made: doubling the concentration of A increases the rate by a factor of 8. doubling the concentration of 8 has no effect on the rate, and doubling the concentration of C increases the rate by a factor of 2. Select the correct rate law for this reaction from the choices below. O Rate-k[A][B][C] O Rate-[A][C] O Rate - K[A]²[C] O Rate = K[A][C]² O Rate = K[A]²[C]² O Rate=K[A] [C] O Rate-k[A][C]³ (c) By what factor will the rate of the reaction described in part (b) above change if the concentrations of A, B, and C are all halved (reduced by a factor of 2)? The rate will be the original rate multiplied by a factor of
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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