a) Which is the acid and which is the base in the reaction? Explain using the appropriate acid / base definitions. (b) A proton is defined as a hard acid. What does this tell you about the properties of [Si9]4-? Explain. (c) [Si9]4- belongs to point group C4v.
a) Which is the acid and which is the base in the reaction? Explain using the appropriate acid / base definitions. (b) A proton is defined as a hard acid. What does this tell you about the properties of [Si9]4-? Explain. (c) [Si9]4- belongs to point group C4v.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(a) Which is the acid and which is the base in the reaction? Explain using the appropriate acid / base definitions.
(b) A proton is defined as a hard acid. What does this tell you about the properties of [Si9]4-? Explain.
(c) [Si9]4- belongs to point group C4v.
1. Describe what will happen to the symmetry elements if one of the atoms is replaced with carbon, as seen in the following figures: (specify which symmetry elements are lost)
2. Is either A or B chiral? Explain.
(d) Using Wade's rules, predict the cluster structure of [Si9]4-. Which borohydride cluster is identiical to the [Si9]4-cluster structure? explain.
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