(a) What type of electrophilic addition to alkenes does fumarase catalyze? (A single phrase only is necessary to answer this.) (b) What feature must the enzyme fumarase exhibit that allows for its enantiospecific catalyzation of this reaction? (One sentence answer.) (c) When the enzyme catalyzed reaction is conducted in D,O, the only product produced is the one shown in the scheme. No other stereoisomer of this molecule is formed. Explain why this is true, in detail (draw!).

(a) What type of electrophilic addition to alkenes does fumarase catalyze? (A single phrase only is necessary to answer this.) (b) What feature must the enzyme fumarase exhibit that allows for its enantiospecific catalyzation of this reaction? (One sentence answer.) (c) When the enzyme catalyzed reaction is conducted in D,O, the only product produced is the one shown in the scheme. No other stereoisomer of this molecule is formed. Explain why this is true, in detail (draw!).

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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