A voltaic cell consists of a Zn/Zn2+Zn/Zn2+ half-cell and a Ni/Ni2+Ni/Ni2+ half-cell at 25 ∘C∘C. The initial concentrations of Ni2+Ni2+ and Zn2+Zn2+ are 1.40 MM and 0.100 MM , respectively. The volume of half-cells is the same. What is the initial cell potential? What is the cell potential when the concentration of Ni2+Ni2+ has fallen to 0.600 MM? What is the concentrations of Ni2+Ni2+ when the cell potential falls to 0.45 VV? What is the concentration of Zn2+Zn2+ when the cell potential falls to 0.45 VV ?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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A voltaic cell consists of a Zn/Zn2+Zn/Zn2+ half-cell and a Ni/Ni2+Ni/Ni2+ half-cell at 25 ∘C∘C. The initial concentrations of Ni2+Ni2+ and Zn2+Zn2+ are 1.40 MM and 0.100 MM , respectively. The volume of half-cells is the same. What is the initial cell potential? What is the cell potential when the concentration of Ni2+Ni2+ has fallen to 0.600 MM? What is the concentrations of Ni2+Ni2+ when the cell potential falls to 0.45 VV? What is the concentration of Zn2+Zn2+ when the cell potential falls to 0.45 VV ?

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