A type of hyperconjugation occurs in the F-CH2-NH¯ anion even though there are no double bonds, triple bonds, or empty p AOs. Draw the orbital interaction that illustrates the most significant hyperconjugation interaction in this species. Hint: What is the HOMO in this species? Which adjacent o* orbital is the lowest in energy?

A type of hyperconjugation occurs in the F-CH2-NH¯ anion even though there are no double bonds, triple bonds, or empty p AOs. Draw the orbital interaction that illustrates the most significant hyperconjugation interaction in this species. Hint: What is the HOMO in this species? Which adjacent o* orbital is the lowest in energy?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Which of these statements concerning p-orbitals is false? 1. They consist of two equivalent lobes. 2. They are absent from the first shell of atomic orbitals. 3. They can form & bonds. 4. They only participate in bonding on carbon atoms. 5. They can hold a maximum of two electrons.
Predict the geometry for each red-highlighted atom and give the hybridization of that center
Q17
See Figure 4-1. Which structure(s) has/have a nitrogen atom that is sp³ hybridized? 0000 A B
Find the following in each compound :A. Draw the overlapping of orbitalsB. Identify the hybrid orbitalC. Identify the molecular orbital
5-3. a. Draw out an empty generic (lollipop shaped) homonuclear diatomic MO diagram like the one used for O2, F2, and Nez. b. Fill this diagram with the appropriate number of valence electrons for [NO]¹ and use it to write out the MO electron configuration for [NO]¹-ion. c. What is the N-O bond order in [NO]¹? d. Will the N-O bond in [NO]¹ be longer or shorter than the N-O bond in the neutral NO molecule? e. How many unpaired electrons are present in [NO]¹? f. Will the unpaired electrons be more concentrated on N or O in [NO]? Explain.
6. Which orbitals overlap to form the carbon-oxygen sigma-bond of acetaldehyde, CH;CHO ? sp3 + sp3 sp? + sp? sp3 + sp? sp+ sp
2- Draw the molecular orbital (MO) electron diagram for the N, molecular ion. Be sure your diagram contains all of the electrons in the ion, including any core electrons. Energy 1 1.
5
Draw an mo diagram for the valence electrons in C2. What is the bond order many sigma and pi bonds are there? What is the HOMO(Highest Occupied Molecular Orbital) and LUMO(Lowest Unoccupied Molecular Orbital)? What is the magnetism of the species?
Draw the molecular orbital (MO) electron diagram for the O2 molecular ion. Be sure your diagram contains all of the electrons in the ion, including any core electrons. Energy 1 L
Which molecule is more polar? Explain.