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a) Transition metal species are classified as Werner or organometallic complexes: Complex Werner Metal Ox. State high low Example Ligand NH.. CO Electrons 12-22 18 Organometallic In organometallic complexes briefly explain how the oxidation state of the meta determines the type of ligand.

a) Transition metal species are classified as Werner or organometallic complexes: Complex Werner Metal Ox. State high low Example Ligand NH.. CO Electrons 12-22 18 Organometallic In organometallic complexes briefly explain how the oxidation state of the meta determines the type of ligand.

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Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Questions about organometallic complexes. a) Transition metal species are classified as Wemer or organometallic complexes: Complex Werner Metal Ox. State high low Example Ligand NH3. CO Electrons 12-22 Organometallic 18 In organometallic complexes briefly explain how the oxidation state of the metal determines the type of ligand. b) Provide the required information regarding the following organometallic compounds. (n²-C2H4)M(CO)3 Missing 2nd-row transition metal M: XH(CO)5 Missing 1"-row transition metal X: [(n°-CSH5)Re(CO);]* Charge on complex z: cis-RuCl2(CO)n Value n: c) The species [(n²-CSH5)Ru(CO)(PME3)]2 has v(CO) bands at 1927 and 1900 cm-!. Propose a structure for this species consistent with the IR data and explain your reasoning.
Transcribed Image Text:Questions about organometallic complexes. a) Transition metal species are classified as Wemer or organometallic complexes: Complex Werner Metal Ox. State high low Example Ligand NH3. CO Electrons 12-22 Organometallic 18 In organometallic complexes briefly explain how the oxidation state of the metal determines the type of ligand. b) Provide the required information regarding the following organometallic compounds. (n²-C2H4)M(CO)3 Missing 2nd-row transition metal M: XH(CO)5 Missing 1"-row transition metal X: [(n°-CSH5)Re(CO);]* Charge on complex z: cis-RuCl2(CO)n Value n: c) The species [(n²-CSH5)Ru(CO)(PME3)]2 has v(CO) bands at 1927 and 1900 cm-!. Propose a structure for this species consistent with the IR data and explain your reasoning.
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