(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך

(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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