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(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך

(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך
Transcribed Image Text:(a) The room temperature and pressure measured rate constants (kobs) for ligand substitution in the square planar platinum(II) complex shown below are given in the Table. By drawing an appropriate diagram to show how the reaction proceeds, explain the trend seen for kobs. Predict what would happen to kobs for chloride substitution if the reaction was performed at high pressure. +ך PENH₂ Kobs NH₂ + X N OMe H2 -NH2 ✗ Table Kobs x 103 / M¹ s¨¹ X 0.45 CH- 3.7 Br 107 I- *ך
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