(a) The physisorption of coronene on Au(111) surface at certain partial pressure of coronene is shown in figure. How does increase or decrease of partial pressure of coronene is expected to change the number of coronene molecules on the gold surface? llustrate with two hypothetical pictures, one for low partial pressure and another one for high partial pressure. (b) The number of moles of active site present on copper surface is 0.002 mol. Assume that 1/2 of the active site is occupied with an air pollutant CH,SH that followed a Langmuir adsorption isotherm. Calculate adsorption binding constant at a CH3SH partial pressure of 16.3 kPa.

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(a) The physisorption of coronene on Au(111) surface at certain partial pressure of coronene is
shown in figure. How does increase or decrease of partial pressure of coronene is expected to
change the number of coronene molecules on the gold surface? Illustrate with two hypothetical
pictures, one for low partial pressure and another one for high partial pressure.
(b) The number of moles of active site present on copper surface is 0.002 mol. Assume that 1/2
of the active site is occupied with an air pollutant CH3SH that followed a Langmuir adsorption
isotherm. Calculate adsorption binding constant at a CH3SH partial pressure of 16.3 kPa.
Transcribed Image Text:(a) The physisorption of coronene on Au(111) surface at certain partial pressure of coronene is shown in figure. How does increase or decrease of partial pressure of coronene is expected to change the number of coronene molecules on the gold surface? Illustrate with two hypothetical pictures, one for low partial pressure and another one for high partial pressure. (b) The number of moles of active site present on copper surface is 0.002 mol. Assume that 1/2 of the active site is occupied with an air pollutant CH3SH that followed a Langmuir adsorption isotherm. Calculate adsorption binding constant at a CH3SH partial pressure of 16.3 kPa.
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