A student runs two experiments with a constant-volume "bomb" calorimeter containing 1300. g of water (see sketch at right). First, a 5.500 g tablet of benzoic acid (CH-CO₂H) is put into the "bomb" and burned completely in an excess of oxygen. (Benzoic acid is known to have a heat of combustion to rise from 24.00 °C to 48.87 °C over a time of 6.3 minutes. 26.454 kJ/g.) The temperature of the water is observed Next, 5.710 g of acetaldehyde (C₂H4O) are put into the "bomb" and similarly completely burned in an excess of oxygen. This time the temperature of the water rises from 24.00 °C to 46.27 °C. Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below about this reaction: 2C₂H₂O(g) 50₂ (8) + - Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in the second experiment. Calculate the reaction enthalpy AHxn per mole of H₂O. O exothermic O endothermic O neither 4CO₂(g) + 4H₂O(g) Be sure any of your answers that are calculated from measured data are rounded to the correct number of significant digits. Note for advanced students: it's possible the student did not do these experiments sufficiently carefully, and the values you calculate may not exactly match published values for this reaction. KJ kJ 0- stirrer mol 0 thermometer chemical reaction "bomb" A "bomb" calorimeter. water insulation.
A student runs two experiments with a constant-volume "bomb" calorimeter containing 1300. g of water (see sketch at right). First, a 5.500 g tablet of benzoic acid (CH-CO₂H) is put into the "bomb" and burned completely in an excess of oxygen. (Benzoic acid is known to have a heat of combustion to rise from 24.00 °C to 48.87 °C over a time of 6.3 minutes. 26.454 kJ/g.) The temperature of the water is observed Next, 5.710 g of acetaldehyde (C₂H4O) are put into the "bomb" and similarly completely burned in an excess of oxygen. This time the temperature of the water rises from 24.00 °C to 46.27 °C. Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below about this reaction: 2C₂H₂O(g) 50₂ (8) + - Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in the second experiment. Calculate the reaction enthalpy AHxn per mole of H₂O. O exothermic O endothermic O neither 4CO₂(g) + 4H₂O(g) Be sure any of your answers that are calculated from measured data are rounded to the correct number of significant digits. Note for advanced students: it's possible the student did not do these experiments sufficiently carefully, and the values you calculate may not exactly match published values for this reaction. KJ kJ 0- stirrer mol 0 thermometer chemical reaction "bomb" A "bomb" calorimeter. water insulation.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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