A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG". • The equilibrium constant K at 25.0 °C. The cell potential under standard conditions E". His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred pef redox reaction is 2. calculated quantities (Check the box next to any that are wrong.) cell AG K E 39 3.92 x 10 A 2. 226. kJ/mol -1.17 V 39 B. 2. 224, kJ/mol 1.75 x 10 -1.16 V C 274. kJ/mol 1.01 x 10 1.42 V

A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG". • The equilibrium constant K at 25.0 °C. The cell potential under standard conditions E". His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred pef redox reaction is 2. calculated quantities (Check the box next to any that are wrong.) cell AG K E 39 3.92 x 10 A 2. 226. kJ/mol -1.17 V 39 B. 2. 224, kJ/mol 1.75 x 10 -1.16 V C 274. kJ/mol 1.01 x 10 1.42 V

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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For a standard voltaic cell comprised of a Cu2+|Cu electrode and a Fe2+|Fe electrode, what is the cell potential, in volts?
A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG. • The equilibrium constant K at 25.0 °C. • The cell potential under standard conditions E°. His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 1. calculated quantities (Check the box next to any that are wrong.) cell n AGº K A 1 -19. kJ/mol 4.69 × 10 0 E 0.20 V 13 B 1 77. kJ/mol 3.09 × 10 0.80 V -14 C 1 75. kJ/mol 7.25 X 10 0.78 V
A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG. The equilibrium constant K at 25:0 °C. The cell potential under standard conditions E His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct.. Also note: for each cell, the number n of electrons transferred per redox reaction is 2. cell n A B C 2 2. 2 calculated quantities. (Check the box next to any that are wrong.) .0 AG 172. kJ/mol J 127. kJ/mol - 170. kJ/mol K -31 7.36 X 10 5:63 X.10 - 23 29 6.06 × 10 - O O E -0.89 V. 0:66 V -0.88. V 5
Consider a voltaic cell in which the reaction is Zn (s) + 2H+ (aq) → Zn2+ (aq) + H2 (g) It is found that the cell voltage is +0.530 V when [Zn2+] = 1.0 M, PH2 = 1.0 atm. What must be the concentration of H+ in the cell? (Use the following information) (Show your work) 2H+ (aq) + 2e- → H2 (g) Eºred = 0.000 V Zn2+ (aq) + 2e- → Zn(s) Eºred = -0.762 V
Based on the sign of the standard cell potential, Eel, classify these reactions as spontaneous or nonspontaneous as written. Assume standard conditions. Refer to the list of standard reduction potentials. Spontaneous as written Nonspontaneous as written Answer Bank Pb2*(aq) + H2(g) - Pb(s) + 2 H*(aq) Ni?*(aq) + s? (aq) Ni(s)+S(s) Al3+(aq) + 3 Na(s) → Al(s) + 3 Na*(aq)
Consider the following electrochemical cell notation with a cell potential of 1.22 V. Pt(s) ∣ H2(g, 1.0 atm) ∣ H+(aq,1.0M) ∣∣ Au3+(aq,? M) ∣ Au (s)Determine the standard cell potential and if the cell is more spontaneous or less spontaneous at standard conditions.
ELECTROCHEMISTRY: Determine the molar mass (amu) of Metal (M) if it took 1.14 minutes for a current of 1.97 A to plate 0.0672 g of metal from a solution containing M2(S04)3 (Round off the final answer to TWO decimal places. Do not include the unit.) A Moving to another question will save this response. «< Question 6 of 12 »
A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AGº. • The equilibrium constant K at 25.0 °C. me 1. ? • The cell potential under standard conditions E°. 00 2. His results are listed below. Ex Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. 000 Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 2. 10 Ar cell n calculated quantities (Check the box next to any that are wrong.) K 0 E 27 A 2 156. kJ/mol O 2.14 X 10 0.81 V 11 B 2 66. kJ/mol O 3.65 × 10 -0.34 V C 2 -264. kJ/mol 46 1.78 x 10 -1.37 V K So Na G 4. 3.
Given the balanced electrochemical reaction below (M and N represent generic metals), what is the cell potential (Ecell), in volts, for this reaction at 35.4 °C when [M+] = 0.00533 M and [N2+] = 0.725 M? Enter your answer to the thousandths place. Do not include units. 2M+(aq) + N(s) → 2M(s) + N2+(aq) E°cell = 0.128 V
A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG • The equilibrium constant K at 25.0 °C.. The cell potential under standard conditions E His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may. assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 1. cell A B C₁ n 1 1. 1 calculated quantities (Check the box next to any that are wrong.) ·a AG 77. kJ/mol O 64. kJ/mol 35. kJ/mol O O K 3.09 X 10 6:13 X 10 13. 6 1.35 X 10 - 12. O X 0. 0.80 V 0.66 V -0.36 V Ś
Enter electrons as e A voltaic cell is constructed in which the anode is a Fe2+|Fe3+ half cell and the cathode is a F|F, half cell. The half-cell compartments are connected by a salt bridge. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) The anode reaction is: The cathode reaction is: The net cell reaction is: +. In the external circuit, electrons migrate the Fe2+|Fe3+ electrode the F|F, electrode. from to In the salt bridge, anions migrate the F|F, compartment 3- the Fe2+|Fe+ compartment. +. +. 1
A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG". • The equilibrium constant K at 25.0 °C. • The cell potential under standard conditions E. His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 1. calculated quantities (Check the box next to any that are wrong.) cell n 46° K 1 - 124. kJ/mol 5.30 x 10 21 -1.28 V -18 4.53 x 10 B 1 - 99. kJ/mol -1.03 V -7 2.20 x 10 1 - 38. kJ/mol 0.39 V