Answered: (a) Strategies the synthesis of the…

(a) Strategies the synthesis of the given transformations to ensure no side-product (provide the reaction and mechanism) : NO2 (i) from quinoline NO2 (i) from pyridine (iii) from Ph CH3 ČH3

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 63AP: As far back as the 16th century, South American Incas chewed the leaves of the coca bush,...

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

( give step by step handwritten solution , these are subpaert do all with detail explanation )

3. (a) Strategies the synthesis of the given
transformations
to
ensure
no
side-product (provide the reaction and
mechanism) :
NO2
(1)
(i)
from quinoline
NO2
from pyridine
(iii)
from
Ph
CH3
ČH3

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22.46 (a&d only)