A standard solution is prepared by completely dissolving 0.4 grams of CaCl2 and 0.2 grams of MgCO3 salts in 1-Liter DI water in a glass bottle closed to the atmosphere. The equilibrium pH of the standard solution is adjusted to 7.3 using acid-base solutions. Assuming the amounts of acid and based used in the initial pH adjustment is negligible, calculate : Temporary and permanent hardness of the solution as mg/L CaCO3.  Total alkalinity and acidity as mg/L CaCO3. Useful information for problem :

Chemistry
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Chapter1: Chemical Foundations
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A standard solution is prepared by completely dissolving 0.4 grams of CaCland 0.2 grams of MgCOsalts in 1-Liter DI water in a glass bottle closed to the atmosphere. The equilibrium pH of the standard solution is adjusted to 7.3 using acid-base solutions. Assuming the amounts of acid and based used in the initial pH adjustment is negligible, calculate :

  1. Temporary and permanent hardness of the solution as mg/L CaCO3. 
  2. Total alkalinity and acidity as mg/L CaCO3.

Useful information for problem : 

 

CT,CO3 = [H₂CO₂] + [HCO3] + [CO²-]
H₂CO3 ↔ HCO3 + H+
= 10-6.3
= 10-10.3
HCO3 ↔ CO²¯ + H+
Και
Kaz
Transcribed Image Text:CT,CO3 = [H₂CO₂] + [HCO3] + [CO²-] H₂CO3 ↔ HCO3 + H+ = 10-6.3 = 10-10.3 HCO3 ↔ CO²¯ + H+ Και Kaz
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