A spent sulfuric acid stream from a nitration process consists of 30. wt% H2SO4 in water. This dilute acid is to be strengthened by the addition of a stream of 90. wt% sulfuric acid, and a stream of 90. wt% nitric acid (HNO). The product stream is to consist of 40. wt% sulfuric acid and 40, wt% nitric acid. The resulting mixture is produced at 100. Ib»/min. Calculate the quantities of spent and concentrated acids that should be mixed to produce the fortified acid mix. Perform a DOF analysis to show tha a solution is possible. You must DRAW A DIAGRAM and SHOW YOUR WORK. Constraints Flow Composition Performance Material Balances Variables Stream System Total Total

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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can u explain the work behind this

 

I don't agree with the system of eqss

 

please expand on them because I'm getting a different number

 

a+b+c=1000

 

c=400/9

A spent sulfuric acid stream from a nitration process consists of 30 wt% H2SO4 in water. This dilute acid is to be strengthened by the addition of a stream of 90 wt% sulfuric acid, and a stream of 90 wt% nitric acid (HNO3). The product stream is to consist of 40 wt% sulfuric acid and 40 wt% nitric acid. The resulting mixture is produced at 100 lb/min. Calculate the quantities of spent and concentrated acids that should be mixed to produce the fortified acid mix. Perform a DOF analysis to show that a solution is possible. You must DRAW A DIAGRAM and SHOW YOUR WORK.

| Variables | Constraints          |
|-----------|----------------------|
| Stream    | Flow                 |
| System    | Composition          |
|           | Performance          |
|           | Material Balances    |
| Total     | Total                |
Transcribed Image Text:A spent sulfuric acid stream from a nitration process consists of 30 wt% H2SO4 in water. This dilute acid is to be strengthened by the addition of a stream of 90 wt% sulfuric acid, and a stream of 90 wt% nitric acid (HNO3). The product stream is to consist of 40 wt% sulfuric acid and 40 wt% nitric acid. The resulting mixture is produced at 100 lb/min. Calculate the quantities of spent and concentrated acids that should be mixed to produce the fortified acid mix. Perform a DOF analysis to show that a solution is possible. You must DRAW A DIAGRAM and SHOW YOUR WORK. | Variables | Constraints | |-----------|----------------------| | Stream | Flow | | System | Composition | | | Performance | | | Material Balances | | Total | Total |
The image contains a flow diagram and accompanying calculations for a chemical process involving sulfuric acid (H₂SO₄) and nitric acid (HNO₃).

### Diagram Explanation:

1. **Flow Diagram:**
   - The diagram is a flowchart with three inlets and one outlet.
   - Inlet A: Contains 30% H₂SO₄.
   - Inlet B: Contains 90% H₂SO₄.
   - Inlet C: Contains 90% HNO₃.
   - The outlet flow is 100 lbm/min with 40% H₂SO₄ and 40% HNO₃.

### Calculations:

1. **Overall HNO₃ Balance:**
   \[
   c \times 0.9 = 100 \times 0.4
   \]
   Solving this gives:
   \[
   c = \frac{400}{a} \, \text{lbm/min}
   \]

2. **H₂SO₄ Balance:**
   \[
   0.3A + 0.9B = 100 \times 0.4 = 40 \quad \text{(Equation 1)}
   \]

3. **Overall Balance:**
   \[
   A + B + C = 100
   \]
   \[
   A + B = 100 - \frac{400}{a} = \frac{500}{a} \quad \text{(Equation 2)}
   \]

4. **Solution from Equations:**
   From Equations 1 and 2:
   \[
   B = 38.888 \, \text{lbm/hr}
   \]
   \[
   A = 16.66 \, \text{lbm/hr}
   \]

5. **Degree of Freedom Analysis:**
   \[
   \text{Degree of freedom} = \text{Number of unknowns} - \text{Number of independent material balance equations}
   \]
   \[
   = 3 \, (A, B, C) - 3 \, (\text{for HNO₃, H₂SO₄, H₂O})
   \]
   Resulting in:
   \[
   \text{Degree of freedom} = 0
   \]

This analysis indicates that the number of independent equations
Transcribed Image Text:The image contains a flow diagram and accompanying calculations for a chemical process involving sulfuric acid (H₂SO₄) and nitric acid (HNO₃). ### Diagram Explanation: 1. **Flow Diagram:** - The diagram is a flowchart with three inlets and one outlet. - Inlet A: Contains 30% H₂SO₄. - Inlet B: Contains 90% H₂SO₄. - Inlet C: Contains 90% HNO₃. - The outlet flow is 100 lbm/min with 40% H₂SO₄ and 40% HNO₃. ### Calculations: 1. **Overall HNO₃ Balance:** \[ c \times 0.9 = 100 \times 0.4 \] Solving this gives: \[ c = \frac{400}{a} \, \text{lbm/min} \] 2. **H₂SO₄ Balance:** \[ 0.3A + 0.9B = 100 \times 0.4 = 40 \quad \text{(Equation 1)} \] 3. **Overall Balance:** \[ A + B + C = 100 \] \[ A + B = 100 - \frac{400}{a} = \frac{500}{a} \quad \text{(Equation 2)} \] 4. **Solution from Equations:** From Equations 1 and 2: \[ B = 38.888 \, \text{lbm/hr} \] \[ A = 16.66 \, \text{lbm/hr} \] 5. **Degree of Freedom Analysis:** \[ \text{Degree of freedom} = \text{Number of unknowns} - \text{Number of independent material balance equations} \] \[ = 3 \, (A, B, C) - 3 \, (\text{for HNO₃, H₂SO₄, H₂O}) \] Resulting in: \[ \text{Degree of freedom} = 0 \] This analysis indicates that the number of independent equations
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The spent acid is mixed with concentrated acid to increase the strength of resulting acid mixture.

 

 

 

 

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