A solution of two diastereomers contains 88.6% of (3S,4S)-tert-butyl-3-amino-4- hydroxypyrrolidine-1-carboxylate and 11.4% of (3S,4R)-tert-butyl-3-amino-4- hydroxypyrrolidine-1-carboxylate. Calculate the percent diastereomeric excess (%d.e.) of the (3S,4S)-tert-butyl-3-amino-4- hydroxypyrrolidine-1-carboxylate in this solution.

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Chapter1: Chemical Foundations
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A solution of two diastereomers contains
88.6% of (3S,4S)-tert-butyl-3-amino-4-
hydroxypyrrolidine-1-carboxylate and 11.4% of
(3S,4R)-tert-butyl-3-amino-4-
hydroxypyrrolidine-1-carboxylate. Calculate
the percent diastereomeric excess (%d.e.) of
the (3S,4S)-tert-butyl-3-amino-4-
hydroxypyrrolidine-1-carboxylate in this
solution.
Transcribed Image Text:A solution of two diastereomers contains 88.6% of (3S,4S)-tert-butyl-3-amino-4- hydroxypyrrolidine-1-carboxylate and 11.4% of (3S,4R)-tert-butyl-3-amino-4- hydroxypyrrolidine-1-carboxylate. Calculate the percent diastereomeric excess (%d.e.) of the (3S,4S)-tert-butyl-3-amino-4- hydroxypyrrolidine-1-carboxylate in this solution.
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