A solution of Ba(OH)2 was standardized against0.1215 g of primary-standard-grade benzoic acid, C6H5COOH (122.12 g/mol). An end point was observedafter addition of 43.25 mL of base. (a) Calculate the molar concentration of the base. (b) Calculate the standard deviation of the molarconcentration if the standard deviation for themass measurement was ±0.3 mg and that for thevolume measurement was ±0.02 mL. (c) Assuming an error of ±0.3 mg in the mass measurement,calculate the absolute and relative systematicerror in the molar concentration.

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A solution of Ba(OH)2 was standardized against
0.1215 g of primary-standard-grade benzoic acid, C6H5COOH (122.12 g/mol). An end point was observed
after addition of 43.25 mL of base.

(a) Calculate the molar concentration of the base.


(b) Calculate the standard deviation of the molar
concentration if the standard deviation for the
mass measurement was ±0.3 mg and that for the
volume measurement was ±0.02 mL.


(c) Assuming an error of ±0.3 mg in the mass measurement,
calculate the absolute and relative systematic
error in the molar concentration.

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