A solution has [Ba2+] = [Sr2+] = 0.10 M. Use data from the following table to choose the best precipitating agent to separate these two ions. Provide computations to prove your answer. E.g. Solve for the concentration of the first ion to precipitate when the second ion begins to precipitate and test for completeness of precipitation of the first ion. C. Solubility Product Constants Name of solute Aluminum hydroxide Aluminum phosphate Barium carbonate Barium chromate Barium fluoride Barium hydroxide Barium sulfate Barium sulfite Barium thiosulfate Bismuthyl chloride Bismuthyl hydroxide Cadmium carbonate Cadmium hydroxide Cadmium sulfideb Calcium carbonate Calcium chromate Calcium fluoride Calcium hydroxide Calcium hydrogen phate Calcium oxalate Calcium phosphate Calcium sulfate Calcium sulfite Chromium(II) hydroxide Chromium(III) hydroxide Cobalt(II) carbonate Cobalt(II) hydroxide Cobalt(III) hydroxide Copper(1) chloride Copper(1) cyanide Copper(1) iodide Copper(II) arsenate Copper(II) carbonate Copper(II) chromate Copper(II) ferrocyanide Copper(II) hydroxide Copper(II) sulfide Iron(II) carbonate Iron(II) hydroxide Iron(II) sulfide Iron(III) arsenate Iron(III) ferrocyanide Iron(III) hydroxide Iron(III) phosphate Lead(II) arsenate Lead(II) azide Lead(II) bromide Lead(II) carbonate Lead(II) chloride Lead(II) chromate Lead(II) fluoride Formula AKOH), AIPO, BaCO, BaCrO₂ BaF₂ Ba(OH)₂ BaSO4 BaSO, Bas₂0 BIOCI BIOOH CdCO, Ca(OH)₂ Cas CaCO CaCrO CaF₂ Ca(OH)₂ CaHPO CaC₂0₁ Cas(PO4)2 CaSO4 Casos Cr(OH)₂ Cr(OH), CoCoj Co(OH)₂ Co(OH), Kup 1.3 x 10 6.3 x 10-19 51 x 10 1.2 x 10-10 CuCl CuCN Cul Cuz(AsO2 CuCOs CuCrO4 Cug[Fe(CN) Cu(OH)₂ Cus FeCO3 Fe(OH)₂ FeS FeAsO4 Fed Fe(CN)els Fe(OH) FePO4 Pb(AsO4)2 Pb(N₂) PbBr₂ PbCO, PbCl₂ PbCrO₂ PbF₂ 1.0 x 10 5 x 10-3 1.1 x 10 10 8x107 1.6 x 10 1.8 x 10 4 x 10-10 5.2 x 10-12 25 x 10-14 8 x 10-2 28 x 10 7.1 x 10 5.3 × 10 5.5 x 106 1 x 107 4x10 20 x 10 9.1 x 106 68 x 10 2 x 10-16 63 x 10 M 1.4 x 10-13 1.6 x 1015 1.6 x 10 1.2 x 10 32 x 10-20 1.1 x 1012 7.6 x 10 % 1.4 x 10 10 36 x 106 1.3 x 1016 22 x 10-20 6 x 10 32 x 10-11 80 x 10-16 6 x 10-19 5.7 x 10 1 33 × 10 4x10 1.3 x 10-22 40 x 10 % 25 x 10 40 x 105 7.4 x 10-14 1.6 x 10 28 x 10-13 2.7 x 10 Name of solute Lead(II) hydroxide Lead(II) iodide Lead(II) sulfate Lead(II) sulfide Lithium carbonate Lithium fluoride Lithium phosphate Magnesium ammonium phosphate Magnesium carbonate Magnesium fluoride Magnesium hydroxide Magnesium phosphate Manganese(II) carbonate Manganese(II) hydroxide Manganese(II) sulfide Mercury(1) bromide Mercury(1) chloride Mercury(1) iodide Mercury(II) sulfide Nickel(II) carbonate Nickel (II) hydroxide Scandium fluoride Scandium hydroxide Silver arsenate Silver azide Silver bromide Silver carbonate Silver chloride Silver chromate Silver cyanide Silver iodate Silver iodide Silver nitrite Silver sulfate Silver sulfide Silver sulfite Silver thiocyanate Strontium carbonate Strontium chromate Strontium fluoride Strontium sulfate Thallium(1) bromide Thallium(1) chloride Thallium(1) iodide Thallium(III) hydroxide Tin(II) hydroxide Tin(II) sulfide Zinc carbonate Zinc hydroxide Zinc oxalate Zinc phosphate Zinc sulfide Kup Formula Pb(OH)₂ Pbl₂ Pb60₁ PbS LigCO, LIF LigPO 1.2 x 10-15 7.1 x 109 1.6 x 10 3 x 10-28 25 x 10-2 3.8 x 103 3.2 x 109 MINH,PO, 25 × 10-13 MgCO, MgF₂ Mg(OH)₂ Mg(PO4)2 MnCO₂ Mn(OH)₂ MnS Hg₂Br₂ HgCl₂ Hala HgS NICO, NI(OH)2 ScFy Sc(OH)s AgsAsO4 AgN₁ AgBr AgaCO₂ AgCl AgaCrO₂ AgCN Aglo, Agl AgNO₂ Ag50₁ Ag₂S Ag SO₂ AgSCN SrCO, SrCrO₂ Sef₂ Sr50 TIBr TICI TII TI(OH), Sn(OH)₂ SnS ZnCO₂ Zn(OH)₂ ZnC₂0₁ Zn(PO4)2 ZnS 3.5 × 10 3.7 x 10 18 x 10-11 1x 10-25 1.8 x 10-11 1.9 x 10-13 3 x 10-14 56 x 10-23 1.3 x 10-18 45 × 10-29 2 x 10-5 66 x 109 20 x 10-15 42 x 10-18 80 x 10-1 1.0 x 10-22 28 x 10 50 x 10-13 8.5 x 10-12 1.8 x 10-10 1.1 x 10-12 1.2 x 10-16 3.0 x 10 85 x 10-17 6.0 x 10 1.4 x 10-5 6 x 105 1.5 x 10-14 1.0 x 10-12 1.1 x 10-10 22 x 105 25 x 10 3.2 x 107 3.4 x 10 1.7 x 10 6.5 x 10 6.3 x 10 1.4 x 10-28 1x 10-2 1.4 x 10-11 1.2 x 10-17 2.7 x 10 90 x 10-33 2 x 10-25

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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SHOW ALL THE COMPUTATIONS. SOLVE IT WITH COMPLETE SOLUTIONS.
SOLVE THE FOLLOWING PROBLEMS AND SHOW YOUR COMPLETE SOLUTIONS. DO NOT COPY
YOUR ANSWERS FROM OTHERS.
2. A solution has [Ba2+] = [Sr2+] = 0.10 M. Use data from the following table to choose the best
precipitating agent to separate these two ions.
Provide computations to prove your answer. E.g. Solve for the concentration of the first ion to
precipitate when the second ion begins to precipitate and test for completeness of precipitation
of the first ion.
C. Solubility Product Constants"
Name of solute
Aluminum hydroxide
Aluminum phosphate
Barium carbonate
Barium chromate
Barium fluoride
Barium hydroxide
Barium sulfate
Barium sulfite
Barium thiosulfate
Bismuthyl chloride
Bismuthyl hydroxide
Cadmium carbonate
Cadmium hydroxide
Cadmium sulfide
Calcium carbonate
Calcium chromate
Calcium fluoride
Calcium hydroxide
Calcium hydrogen
phosphate
Calcium oxalate
Calcium phosphate
Calcium sulfate
Calcium sulfite
Chromium(II) hydroxide
Chromium(III) hydroxide
Cobalt(II) carbonate
Cobalt(II) hydroxide
Cobalt(III) hydroxide
Copper(1) chloride
Copper(1) cyanide
Copper(1) iodide
Copper(II) arsenate
Copper(II) carbonate
Copper(II) chromate
Copper(II) ferrocyanide
Copper(II) hydroxide
Copper(II) sulfide
Iron(II) carbonate
Iron(II) hydroxide
Iron(II) sulfide
Iron(III) arsenate
Iron(III) ferrocyanide
Iron(III) hydroxide
Iron(III) phosphate
Lead(II) arsenate
Lead(II) azide
Lead(II) bromide
Lead(II) carbonate
Lead(II) chloride
Lead(II) chromate
Lead(II) fluoride
Formula
AK(OH)3
AIPO4
BaCO₂
BaCrO₂
BaF₂
Ba(OH)₂
BaSO4
BaSO3
BaS₂0
BIOCI
BIOOH
CdCO
Cd(OH)₂
Cas
CaCO3
CaCrO4
CaF₂
Ca(OH)₂
C₂HPO4
CaC₂04
Ca3(PO4)2
CaSO4
CaSO3
Cr(OH)₂
Cr(OH)3
COCO,
Co(OH)₂
Co(OH),
CuCl
CUCN
Cul
Cu₂(AsO4)2
CuCO₂
CuCrO₂
Cu[Fe(CN)6
Cu(OH)₂
Cus
FeCO3
Fe(OH)₂
Fes
1.3 x 10-
6.3 x 10-19
5.1 x 109
1.2 x 10-10
FeAsO4
Fed Fe(CN)als
Fe(OH)3
FePO4
PbAsO4)2
Pb(N₂)₂
PbBr₂
PbCO3
PbCl₂
PbCrO4
PbF₂
1.0 x 10
5 x 10-3
1.1 x 10-10
8 x 10-7
1.6 x 10-5
1.8 x 10-31
4 x 10-10
5.2 x 10-12
25 x 10-14
8 x 10-2
28 x 109
7.1 x 10
5.3 x 109
5.5 x 10-6
1 x 107
4 x 10
20 x 1029
9.1 x 106
6.8 x 10
2x 10-16
6.3 x 10-31
1.4 x 10-13
1.6 x 10-15
1.6 x 10-4
1.2 x 106
3.2 x 10-20
1.1 x 10-12
7.6 x 10 %
1.4 x 10-10-
36 x 106
1.3 x 10-16
22 x 10-20
6 x 10
32 x 10-11
80 x 10-16
6 x 10-19
5.7 x 10-21
33 x 10
4x10 38
1.3 x 10-22
40 x 10 %
25 x 109
40 x 10-5
7.4 x 10-14
1.6 x 10-5
28 x 10-137
2.7 x 10
Name of solute
Lead(II) hydroxide
Lead(II) iodide
Lead(II) sulfate
Lead(II) sulfide
Lithium carbonate
Lithium fluoride
Lithium phosphate
Magnesium
ammonium phosphate
Magnesium carbonate
Magnesium fluoride
Magnesium hydroxide
Magnesium phosphate
Manganese(II) carbonate
Manganese(II) hydroxide
Manganese(II) sulfide
Mercury(1) bromide
Mercury(1) chloride.
Mercury(1) iodide
Mercury(II) sulfide
Nickel(II) carbonate
Nickel(II) hydroxide
Scandium fluoride
Scandium hydroxide
Silver arsenate
Silver azide
Silver bromide
Silver carbonate
Silver chloride
Silver chromate
Silver cyanide
Silver iodate
Silver iodide
Silver nitrite
Silver sulfate
Silver sulfide
Silver sulfite
Silver thiocyanate
Strontium carbonate
Strontium chromate
Strontium fluoride
Strontium sulfate
Thallium(1) bromide
Thallium(I) chloride
Thallium(1) iodide
Thallium(III) hydroxide
Tin(II) hydroxide
Tin(II) sulfideb
Zinc carbonate
Zinc hydroxide
Zinc oxalate
Zinc phosphate
Zinc sulfide
Formula
Pb(OH)₂
Pbl₂
PbSO4
PbS
Li₂CO3
LIF
Li PO4
MẠNHPO,
MgCO3
MgF₂
Mg(OH)₂
Mg3(PO4)2
MnCO3
Mn(OH)₂
MnS
Hg₂Br₂
Hg₂Cl₂
Hgala
HgS
NICO,
NI(OH)₂
ScF3
Sc(OH)3
Ag AsO4
AgN₁
AgBr
AgaCO₂
AgCl
AgaCrO4
AgCN
AgI03
Agl
AgNO₂
Ag SO₂
Ag S
Ag SO₂
AgSCN
SrCO,
SrCrO4
SrF₂
SISO
TIBr
TICI
TII
TI(OH)3
Sn(OH)2
SnS
ZnCO₂
Zn(OH)₂
ZnC₂04
Zn (PO4)2
ZnS
Kup
1.2 x 10-15
7.1 x 109
1.6 x 108
3 x 10-28
2.5 x 10-2
3.8 x 10-3
3.2 x 109
25 × 101
3.5 x 10-
3.7 x 108
1.8 x 10-11
1 x 10-25
1.8 x 10-11
1.9 x 10-13
3 x 10-14
5.6 x 10-23
1.3 x 10-18
45 x 10-29
2x 10-5
6.6 x 109
20 x 10-15
42 x 10-18
8.0 x 10 31
1.0 x 10-22
28 x 109
5.0 x 10-13
8.5 x 10-12
1.8 x 10-10
1.1 x 10-12
1.2 x 10-16
3.0 x 108
8.5 x 10-17
6.0 x 10
1.4 x 10-5
6 x 10-51
1.5 x 10-14
1.0 x 10-12
1.1 x 10-10
22 x 105
25 x 109
3.2 x 107
3.4 x 10-6
1.7 x 10
6.5 x 108
6.3 x 10
1.4 x 10-28
1 x 10-2
1.4 x 10-11
1.2 x 10-17
2.7 x 10
9.0 × 10-33
2x 10-25
Transcribed Image Text:SOLVE THE FOLLOWING PROBLEMS AND SHOW YOUR COMPLETE SOLUTIONS. DO NOT COPY YOUR ANSWERS FROM OTHERS. 2. A solution has [Ba2+] = [Sr2+] = 0.10 M. Use data from the following table to choose the best precipitating agent to separate these two ions. Provide computations to prove your answer. E.g. Solve for the concentration of the first ion to precipitate when the second ion begins to precipitate and test for completeness of precipitation of the first ion. C. Solubility Product Constants" Name of solute Aluminum hydroxide Aluminum phosphate Barium carbonate Barium chromate Barium fluoride Barium hydroxide Barium sulfate Barium sulfite Barium thiosulfate Bismuthyl chloride Bismuthyl hydroxide Cadmium carbonate Cadmium hydroxide Cadmium sulfide Calcium carbonate Calcium chromate Calcium fluoride Calcium hydroxide Calcium hydrogen phosphate Calcium oxalate Calcium phosphate Calcium sulfate Calcium sulfite Chromium(II) hydroxide Chromium(III) hydroxide Cobalt(II) carbonate Cobalt(II) hydroxide Cobalt(III) hydroxide Copper(1) chloride Copper(1) cyanide Copper(1) iodide Copper(II) arsenate Copper(II) carbonate Copper(II) chromate Copper(II) ferrocyanide Copper(II) hydroxide Copper(II) sulfide Iron(II) carbonate Iron(II) hydroxide Iron(II) sulfide Iron(III) arsenate Iron(III) ferrocyanide Iron(III) hydroxide Iron(III) phosphate Lead(II) arsenate Lead(II) azide Lead(II) bromide Lead(II) carbonate Lead(II) chloride Lead(II) chromate Lead(II) fluoride Formula AK(OH)3 AIPO4 BaCO₂ BaCrO₂ BaF₂ Ba(OH)₂ BaSO4 BaSO3 BaS₂0 BIOCI BIOOH CdCO Cd(OH)₂ Cas CaCO3 CaCrO4 CaF₂ Ca(OH)₂ C₂HPO4 CaC₂04 Ca3(PO4)2 CaSO4 CaSO3 Cr(OH)₂ Cr(OH)3 COCO, Co(OH)₂ Co(OH), CuCl CUCN Cul Cu₂(AsO4)2 CuCO₂ CuCrO₂ Cu[Fe(CN)6 Cu(OH)₂ Cus FeCO3 Fe(OH)₂ Fes 1.3 x 10- 6.3 x 10-19 5.1 x 109 1.2 x 10-10 FeAsO4 Fed Fe(CN)als Fe(OH)3 FePO4 PbAsO4)2 Pb(N₂)₂ PbBr₂ PbCO3 PbCl₂ PbCrO4 PbF₂ 1.0 x 10 5 x 10-3 1.1 x 10-10 8 x 10-7 1.6 x 10-5 1.8 x 10-31 4 x 10-10 5.2 x 10-12 25 x 10-14 8 x 10-2 28 x 109 7.1 x 10 5.3 x 109 5.5 x 10-6 1 x 107 4 x 10 20 x 1029 9.1 x 106 6.8 x 10 2x 10-16 6.3 x 10-31 1.4 x 10-13 1.6 x 10-15 1.6 x 10-4 1.2 x 106 3.2 x 10-20 1.1 x 10-12 7.6 x 10 % 1.4 x 10-10- 36 x 106 1.3 x 10-16 22 x 10-20 6 x 10 32 x 10-11 80 x 10-16 6 x 10-19 5.7 x 10-21 33 x 10 4x10 38 1.3 x 10-22 40 x 10 % 25 x 109 40 x 10-5 7.4 x 10-14 1.6 x 10-5 28 x 10-137 2.7 x 10 Name of solute Lead(II) hydroxide Lead(II) iodide Lead(II) sulfate Lead(II) sulfide Lithium carbonate Lithium fluoride Lithium phosphate Magnesium ammonium phosphate Magnesium carbonate Magnesium fluoride Magnesium hydroxide Magnesium phosphate Manganese(II) carbonate Manganese(II) hydroxide Manganese(II) sulfide Mercury(1) bromide Mercury(1) chloride. Mercury(1) iodide Mercury(II) sulfide Nickel(II) carbonate Nickel(II) hydroxide Scandium fluoride Scandium hydroxide Silver arsenate Silver azide Silver bromide Silver carbonate Silver chloride Silver chromate Silver cyanide Silver iodate Silver iodide Silver nitrite Silver sulfate Silver sulfide Silver sulfite Silver thiocyanate Strontium carbonate Strontium chromate Strontium fluoride Strontium sulfate Thallium(1) bromide Thallium(I) chloride Thallium(1) iodide Thallium(III) hydroxide Tin(II) hydroxide Tin(II) sulfideb Zinc carbonate Zinc hydroxide Zinc oxalate Zinc phosphate Zinc sulfide Formula Pb(OH)₂ Pbl₂ PbSO4 PbS Li₂CO3 LIF Li PO4 MẠNHPO, MgCO3 MgF₂ Mg(OH)₂ Mg3(PO4)2 MnCO3 Mn(OH)₂ MnS Hg₂Br₂ Hg₂Cl₂ Hgala HgS NICO, NI(OH)₂ ScF3 Sc(OH)3 Ag AsO4 AgN₁ AgBr AgaCO₂ AgCl AgaCrO4 AgCN AgI03 Agl AgNO₂ Ag SO₂ Ag S Ag SO₂ AgSCN SrCO, SrCrO4 SrF₂ SISO TIBr TICI TII TI(OH)3 Sn(OH)2 SnS ZnCO₂ Zn(OH)₂ ZnC₂04 Zn (PO4)2 ZnS Kup 1.2 x 10-15 7.1 x 109 1.6 x 108 3 x 10-28 2.5 x 10-2 3.8 x 10-3 3.2 x 109 25 × 101 3.5 x 10- 3.7 x 108 1.8 x 10-11 1 x 10-25 1.8 x 10-11 1.9 x 10-13 3 x 10-14 5.6 x 10-23 1.3 x 10-18 45 x 10-29 2x 10-5 6.6 x 109 20 x 10-15 42 x 10-18 8.0 x 10 31 1.0 x 10-22 28 x 109 5.0 x 10-13 8.5 x 10-12 1.8 x 10-10 1.1 x 10-12 1.2 x 10-16 3.0 x 108 8.5 x 10-17 6.0 x 10 1.4 x 10-5 6 x 10-51 1.5 x 10-14 1.0 x 10-12 1.1 x 10-10 22 x 105 25 x 109 3.2 x 107 3.4 x 10-6 1.7 x 10 6.5 x 108 6.3 x 10 1.4 x 10-28 1 x 10-2 1.4 x 10-11 1.2 x 10-17 2.7 x 10 9.0 × 10-33 2x 10-25
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