A solution contains some or all of the ions Cu²*, AP+, K*, Ca²+, Ba", Pb, and NH,* The following tests were performed, in order, on the solution. 1. Addition of 6 M HCl produced no reaction 2. Addition of H,S with 02 M HCl produced a black solid. 3. Addition of (NH,),S produced a white solid 4. Addition of (NH,),HPO, in NH, produced no reaction. 5. The final supenatant when heated produced a purple flame Identify which of these ions were present in the solution, which were absent, and for which ones no conclusions can be drawn
A solution contains some or all of the ions Cu²*, AP+, K*, Ca²+, Ba", Pb, and NH,* The following tests were performed, in order, on the solution. 1. Addition of 6 M HCl produced no reaction 2. Addition of H,S with 02 M HCl produced a black solid. 3. Addition of (NH,),S produced a white solid 4. Addition of (NH,),HPO, in NH, produced no reaction. 5. The final supenatant when heated produced a purple flame Identify which of these ions were present in the solution, which were absent, and for which ones no conclusions can be drawn
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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I need help with all parts of number 13
![Ag', Pb, Hg
Cu, Bi", Cd³; Pb*; Hg²,H;AsO;", AsO, , Sb", Sn, Sn
Al", Fe", Fe", Co", Ni²', Cr", Zn²“, Mn²'
Ba, Ca, Mg*
| Na", K', NH,
Add H,S,
0.2 M HCI
Add (NH,),S,
pH 8
Add (NH,);HPO,
NH,
Add 6 M HCI
Remaining
cations
Remaining
cations
Remaining
cations
Group 5-Alkali metal
ions and NH,":
Na, K, NH,
Precipitàte
V Precipitate
Precipitate
Precipitate
Group 2-Acid-insoluble
sulfides: Cus, Bi, S, Cds, PbS,
HgS, As-S, Sb,S, SnS
Group 3-Base-insoluble sulfides
and hydroxides: Al(OH), Fe(OH),
Cr(OH), ZnS, Nis, Cos, MnS
Group 4-Insoluble
phosphates: Ba-(PO
Group 1-
Insoluble chlorides:
Ca(PO,, MENH,PO,
ABCI, Hg,Cl, PBCI,
Some ions that are soluble in all of the test solutions can still be identified based on flame tests. Certain ions impart characteristic color to the flame.
Metal cation Flame color
Li
red
Na
yellow
K
purple
Part A
A solution contains some or all of the ions Cu+, AP+, K*, Ca2+, Ba?+, Pb?+ and NH,. The following tests were performed, in order, on the solution.
1. Addition of 6 M HCl produced no reaction.
2. Addition of H,S with 02 M HCl produced a black solid.
3. Addition of (NH,),S produced a white solid
4. Addition of (NH,),HPO, in NH3 produced no reaction.
5. The final supernatant when heated produced a purple flame.
Identify which of these ions were present in the solution, which were absent, and for which ones no conclusions can be drawn.
Drag the appropriate items to their respective bins.
> View Available Hint(s)
Reset Help
Ca
Pha Ba NH,
K Cu
AP
Inconclusive
Absent
Present
P Type here to search](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc4301313-6c09-4f87-b4dd-6d1d15a5f2d7%2F0b0a77d3-119d-4053-9347-0fb967fe37e6%2F9no7hct_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Ag', Pb, Hg
Cu, Bi", Cd³; Pb*; Hg²,H;AsO;", AsO, , Sb", Sn, Sn
Al", Fe", Fe", Co", Ni²', Cr", Zn²“, Mn²'
Ba, Ca, Mg*
| Na", K', NH,
Add H,S,
0.2 M HCI
Add (NH,),S,
pH 8
Add (NH,);HPO,
NH,
Add 6 M HCI
Remaining
cations
Remaining
cations
Remaining
cations
Group 5-Alkali metal
ions and NH,":
Na, K, NH,
Precipitàte
V Precipitate
Precipitate
Precipitate
Group 2-Acid-insoluble
sulfides: Cus, Bi, S, Cds, PbS,
HgS, As-S, Sb,S, SnS
Group 3-Base-insoluble sulfides
and hydroxides: Al(OH), Fe(OH),
Cr(OH), ZnS, Nis, Cos, MnS
Group 4-Insoluble
phosphates: Ba-(PO
Group 1-
Insoluble chlorides:
Ca(PO,, MENH,PO,
ABCI, Hg,Cl, PBCI,
Some ions that are soluble in all of the test solutions can still be identified based on flame tests. Certain ions impart characteristic color to the flame.
Metal cation Flame color
Li
red
Na
yellow
K
purple
Part A
A solution contains some or all of the ions Cu+, AP+, K*, Ca2+, Ba?+, Pb?+ and NH,. The following tests were performed, in order, on the solution.
1. Addition of 6 M HCl produced no reaction.
2. Addition of H,S with 02 M HCl produced a black solid.
3. Addition of (NH,),S produced a white solid
4. Addition of (NH,),HPO, in NH3 produced no reaction.
5. The final supernatant when heated produced a purple flame.
Identify which of these ions were present in the solution, which were absent, and for which ones no conclusions can be drawn.
Drag the appropriate items to their respective bins.
> View Available Hint(s)
Reset Help
Ca
Pha Ba NH,
K Cu
AP
Inconclusive
Absent
Present
P Type here to search
![Part B
Select the reagent that will separate the pairs of ions listed.
Drag each label to the appropriate target.
> View Available Hint(s)
6 M HCI
Ions
Reagent
Ag and Al3
H2S, 0.2 M HCI
Cu and Ca
(NH4)2S, pH 8
Mg and K*
(NH,)2HPO, in NH
Ni? and Co
Cannot be separated](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc4301313-6c09-4f87-b4dd-6d1d15a5f2d7%2F0b0a77d3-119d-4053-9347-0fb967fe37e6%2Fcj8xqfc_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Part B
Select the reagent that will separate the pairs of ions listed.
Drag each label to the appropriate target.
> View Available Hint(s)
6 M HCI
Ions
Reagent
Ag and Al3
H2S, 0.2 M HCI
Cu and Ca
(NH4)2S, pH 8
Mg and K*
(NH,)2HPO, in NH
Ni? and Co
Cannot be separated
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