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A small reaction bomb fitted with a sensitive pressure-measuring device is flushed out and then filled with pure reactant A at 1-atm pressure. The operation is carried out at 25°C, a temperature low enough that the reaction does not proceed to any appreciable extent. The temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water, and the readings in Table P3.21 are obtained. The stoichiometry of the reaction is 2A → B, and after leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found. Find a rate equation in units of moles, liters, and minutes which will satisfactorily fit the data. Table P3.21 T, min TT, atm Т, min TT, atm 0.850 0.832 1 1.14 7 2 1.04 8. 0.982 0.815 4 0.940 10 0.800 0.754 0.728 0.905 15 6. 0.870 20

A small reaction bomb fitted with a sensitive pressure-measuring device is flushed out and then filled with pure reactant A at 1-atm pressure. The operation is carried out at 25°C, a temperature low enough that the reaction does not proceed to any appreciable extent. The temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water, and the readings in Table P3.21 are obtained. The stoichiometry of the reaction is 2A → B, and after leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found. Find a rate equation in units of moles, liters, and minutes which will satisfactorily fit the data. Table P3.21 T, min TT, atm Т, min TT, atm 0.850 0.832 1 1.14 7 2 1.04 8. 0.982 0.815 4 0.940 10 0.800 0.754 0.728 0.905 15 6. 0.870 20

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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3.21. A small reaction bomb fitted with a sensitive pressure-measuring device is flushed out and then filled with pure reactant A at 1-atm pressure. The operation is carried out at 25°C, a temperature low enough that the reaction does not proceed to any appreciable extent. The temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water, and the readings in Table P3.21 are obtained. The stoichiometry of the reaction is 2A → B, and after leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found. Find a rate equation in units of moles, liters, and minutes which will satisfactorily fit the data. Table P3.21 Т, min TT, atm Т, min п, atm 1 1.14 7 0.850 2 1.04 8 0.832 3 0.982 9. 0.815 4 0.940 10 0.800 5 0.905 15 0.754 6. 0.870 20 0.728
Transcribed Image Text:3.21. A small reaction bomb fitted with a sensitive pressure-measuring device is flushed out and then filled with pure reactant A at 1-atm pressure. The operation is carried out at 25°C, a temperature low enough that the reaction does not proceed to any appreciable extent. The temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water, and the readings in Table P3.21 are obtained. The stoichiometry of the reaction is 2A → B, and after leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found. Find a rate equation in units of moles, liters, and minutes which will satisfactorily fit the data. Table P3.21 Т, min TT, atm Т, min п, atm 1 1.14 7 0.850 2 1.04 8 0.832 3 0.982 9. 0.815 4 0.940 10 0.800 5 0.905 15 0.754 6. 0.870 20 0.728
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