A small pump is used to pump ambient air at 20°C into a 0.10 m³ tank at a constant volumetric flow rate of Q = 0.10 m³/min. The tank pressure is initially at 1 atm. Determine the time required to raise the pressure in the tank to 10 atm. Assume the gas in the tank remains at a constant temperature of 20°C.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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So the problem is an Unsteady-State Mass Conservation problem? My professor only taught us how to do steady state where accumulation is zero, so I dont know what to do.

A small pump is used to pump ambient air at 20°C into a 0.10 m³ tank at a constant
volumetric flow rate of Q = 0.10 m³/min. The tank pressure is initially at 1 atm. Determine
the time required to raise the pressure in the tank to 10 atm. Assume the gas in the tank
remains at a constant temperature of 20°C.
Transcribed Image Text:A small pump is used to pump ambient air at 20°C into a 0.10 m³ tank at a constant volumetric flow rate of Q = 0.10 m³/min. The tank pressure is initially at 1 atm. Determine the time required to raise the pressure in the tank to 10 atm. Assume the gas in the tank remains at a constant temperature of 20°C.
Expert Solution
Step 1

Given: Volumetric flow rate of air Q = 0.10 m3/min

Tank Volume V = 0.10 m3

The temperature of air entering and tank T = 20°C = 293.15 K

Initial Pressure P1 = 1 atm

Final Pressure P= 10 atm

To determine, the time required to raise the pressure t =?

Schematic for the given problem can be shown as below:Chemical Engineering homework question answer, step 1, image 1

Step 2

Please note that the final volume of gas inside the tank would be equal to tank volume, at higher pressure. Hence the initial and final volume in the tank is the same. Please don't confuse as more flow in coming in, the volume should be high, as additional volume is utilized in increasing the pressure of the tank.

Here we will first find out the difference in moles of initially in the tank (ni) and finally in the tank (nf).

From ideal gas law, we know: 

PV=nRTn=PVRT

So, nf-ni=VRT(P2-P1)where R is universal gas constant = 8.314 J/mol/K. Also as 1 atm = 101325 Pa,sustituting values in above equation  nf-ni=0.108.314×293.15(10×101325-1×101325)n=37.42 mol

Now, assuming the flow coming in at 1 atm, and as given at 20°C

Total volume of gas entered to change the number of moles inside would be as below:

Vt=nRTPVt=37.42×8.314×293.15101325Vt=0.9 m3

 

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