(а) Show the electron counting for the metal center of each of the complexes below by using the ionic model. The answer should include the formal oxidation state of the metal, the number ofd electrons, ligand charges (if present) and the total electron count.

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Chapter1: Chemical Foundations
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Show the electron counting for the metal center of each of the complexes
below by using the ionic model. The answer should include the formal
oxidation state of the metal, the number of d electrons, ligand charges (if
present) and the total electron count.
QI.
(а)
(i)
(ii)
R2
Pl
MECN-
MeCN
NCME
(iii)
Me
Me
Rh
(b)
Given a pair of metal hydride complexes:
1f-Cp*Ru(H)(PME3)2 or V(H)(CO),
(where Cp* =C3Mes)
Choose the complex with the lower pKa value and explain why.
-C=O
Transcribed Image Text:Show the electron counting for the metal center of each of the complexes below by using the ionic model. The answer should include the formal oxidation state of the metal, the number of d electrons, ligand charges (if present) and the total electron count. QI. (а) (i) (ii) R2 Pl MECN- MeCN NCME (iii) Me Me Rh (b) Given a pair of metal hydride complexes: 1f-Cp*Ru(H)(PME3)2 or V(H)(CO), (where Cp* =C3Mes) Choose the complex with the lower pKa value and explain why. -C=O
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