(a) Show that when an ideal gas expands adiabatically, the temperature and pressure are related by the differential equation dT 2 T dP f+2 P

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Chapter1: Chemical Foundations
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Suppose you have calculated the pressure of earth's atmosphere as a function of altitude, assuming constant temperature. Ordinarily, however, the temperature of the bottommost 10-15 km of the atmosphere (called the troposphere) decreases with increasing altitude, due to heating from the ground (which is warmed by sunlight). If the temperature gradient IdT/dzl exceeds a certain critical value, convection will occur: Warm, low-density air will rise, while cool, high-density air sinks. The decrease of pressure with altitude causes a rising air mass to expand adiabatically and thus to cool. The condition for convection to occur is that the rising air mass must remain warmer than the surrounding air despite this adiabatic cooling.

Show that when an ideal gas expands adiabatically, the temperature and pressure are related by the differential equation

(a) Show that when an ideal gas expands adiabatically, the temperature and
pressure are related by the differential equation
dT
2 T
dP
f+2 P
Transcribed Image Text:(a) Show that when an ideal gas expands adiabatically, the temperature and pressure are related by the differential equation dT 2 T dP f+2 P
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