Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:5. In the radical addition of HBr to alkenes, we saw benzoyl peroxide as a radical
initiator. The reaction below uses a different radical initiator:
HBr
.CN
NC
`N´
(radical initiator)
The reaction showing the formation of the initial radicals using this initiator is shown
below:
CN
NEN
2 х
NC
+
NC
a) Show a detailed mechanism for the reaction to produce nitrogen gas and the two
carbon radicals shown above.
b) Show how the carbon radical produced above could react with HBr to make a bromine
radical, completing the initiation step for the reaction at the top of the page.
c) Show a detailed mechanism for the propagation step of the reaction at the top of the
page and circle the major organic product produced from the reaction.
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