A sample of pure solid naphthalene (C1,Hg) weighing 0.6410 g is burned completely with oxygen to CO2(g) and H,O(€) in a constant-volume calorimeter at 25°C. The amount of heat evolved is observed to be 25.79 kJ. (a) Write and balance the chemical equation for the com- bustion reaction. (b) Calculate the standard change in internal energy (AU°) for the combustion of 1.000 mol naphthalene to CO2(g) and H,O(€). (c) Calculate the standard enthalpy change (AH°) for the same reaction as in part (b). (d) Calculate the standard enthalpy of formation per mole of naphthalene, using data for the standard enthalpies of formation of CO2(g) and H,O(€) from Appendix D.

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A sample of pure solid naphthalene (C1,Hg) weighing
0.6410 g is burned completely with oxygen to CO2(g) and
H,O(€) in a constant-volume calorimeter at 25°C. The
amount of heat evolved is observed to be 25.79 kJ.
(a) Write and balance the chemical equation for the com-
bustion reaction.
(b) Calculate the standard change in internal energy
(AU°) for the combustion of 1.000 mol naphthalene
to CO2(g) and H,O(€).
(c) Calculate the standard enthalpy change (AH°) for the
same reaction as in part (b).
(d) Calculate the standard enthalpy of formation per
mole of naphthalene, using data for the standard
enthalpies of formation of CO2(g) and H,O(€) from
Appendix D.
Transcribed Image Text:A sample of pure solid naphthalene (C1,Hg) weighing 0.6410 g is burned completely with oxygen to CO2(g) and H,O(€) in a constant-volume calorimeter at 25°C. The amount of heat evolved is observed to be 25.79 kJ. (a) Write and balance the chemical equation for the com- bustion reaction. (b) Calculate the standard change in internal energy (AU°) for the combustion of 1.000 mol naphthalene to CO2(g) and H,O(€). (c) Calculate the standard enthalpy change (AH°) for the same reaction as in part (b). (d) Calculate the standard enthalpy of formation per mole of naphthalene, using data for the standard enthalpies of formation of CO2(g) and H,O(€) from Appendix D.
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