A sample of 70 mmol Kr (g) expands reversibly and isothermally at 100 °C from 5.25 cm3 to 6.29 cm³, and the internal energy of the sample is known to increase by 83.5 J. Use the virial equation of state up to the second coefficient B =-28.7 cm3 mol- to calculate w, q, and AH for this change of state. The virial equation truncated to the second coefficient is given by: RT В 1+ Vm т

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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A sample of 70 mmol Kr (g) expands reversibly and isothermally at 100 °C
from 5.25 cm3 to 6.29 cm³, and the internal energy of the sample is known to increase by
83.5 J. Use the virial equation of state up to the second coefficient B =-28.7 cm3 mol- to
calculate w, q, and AH for this change of state. The virial equation truncated to the second
coefficient is given by:
RT
p =
В
1+
Vm
т
Transcribed Image Text:A sample of 70 mmol Kr (g) expands reversibly and isothermally at 100 °C from 5.25 cm3 to 6.29 cm³, and the internal energy of the sample is known to increase by 83.5 J. Use the virial equation of state up to the second coefficient B =-28.7 cm3 mol- to calculate w, q, and AH for this change of state. The virial equation truncated to the second coefficient is given by: RT p = В 1+ Vm т
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