A proposed mechanism for the gas phase reaction of chloroform (CHCl3) and chlorine is as follows: 1. Cl2 (g) ⇌ 2 Cl (g) fast 2. Cl(g) + CHCl3(g) → HCl(g) + CCl3(g) slow 3. Cl (g) + CCl3 (g) → CCl4 (g) fast 5. What is the rate law for the overall reaction in Question #4? A. k [Cl2] B. k [Cl2][CHCl3] C. k [CHCl3][Cl2]2 D. k [Cl][CCl3] E. k [CHCl3][Cl2]1/2
A proposed mechanism for the gas phase reaction of chloroform (CHCl3) and chlorine is as follows: 1. Cl2 (g) ⇌ 2 Cl (g) fast 2. Cl(g) + CHCl3(g) → HCl(g) + CCl3(g) slow 3. Cl (g) + CCl3 (g) → CCl4 (g) fast 5. What is the rate law for the overall reaction in Question #4? A. k [Cl2] B. k [Cl2][CHCl3] C. k [CHCl3][Cl2]2 D. k [Cl][CCl3] E. k [CHCl3][Cl2]1/2
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 80QAP: Two mechanisms are proposed for the reaction 2NO(g)+O2(g)2NO2(g)Mechanism 1: NO+O2NO3(fast)...
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Question
A proposed mechanism for the gas phase reaction
of chloroform (CHCl3) and chlorine is as follows:
1. Cl2 (g) ⇌ 2 Cl (g) fast
2. Cl(g) + CHCl3(g) → HCl(g) + CCl3(g) slow
3. Cl (g) + CCl3 (g) → CCl4 (g) fast
5. What is the rate law for the overall reaction in
Question #4?
A. k [Cl2]
B. k [Cl2][CHCl3]
C. k [CHCl3][Cl2]2
D. k [Cl][CCl3]
E. k [CHCl3][Cl2]1/2
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