À proposed mechanism for the destruction of ozone is given by the gas-phase reaction HO (g) + O3 (g)→OH (g) + 2 02 (g) The initial rate of this reaction has been determined in several experiments, as shown in the table. [HO2:] [03] (molecules (molecules cm 3) Rate (molecules cm-3 s1) cm 3)

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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A proposed mechanism for the destruction of ozone is given by the gas-phase reaction
HO (g) + O3 (g)→OH (g) + 2 02 (g)
The initial rate of this reaction has been determined in several experiments, as shown in
the table.
[HO2:]
[O3]
(molecules (molecules
cm 3)
Rate (molecules
cm 3 s1)
cm 3)
1.0 x 1011
1.0 x 1012
1.9 x 108
1.0 x 1011
5.0 x 1012
9.5 x 108
3.0 x 1011
1.0 x 1012
5.7 x 108
a) Give the initial orders of reaction with respect to the two reactants and explain how
you got those values.
b) What is the rate constant for this reaction under the quoted conditions?
Transcribed Image Text:A proposed mechanism for the destruction of ozone is given by the gas-phase reaction HO (g) + O3 (g)→OH (g) + 2 02 (g) The initial rate of this reaction has been determined in several experiments, as shown in the table. [HO2:] [O3] (molecules (molecules cm 3) Rate (molecules cm 3 s1) cm 3) 1.0 x 1011 1.0 x 1012 1.9 x 108 1.0 x 1011 5.0 x 1012 9.5 x 108 3.0 x 1011 1.0 x 1012 5.7 x 108 a) Give the initial orders of reaction with respect to the two reactants and explain how you got those values. b) What is the rate constant for this reaction under the quoted conditions?
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