A process for the production of 1,3-butadiene results from the catalytic dehydrogenation at atmospheric pressure of 1-butene according to the reaction: C4H8(g) → C4H6(g) + H2(g), heat of reaction is 109780 J/mol. To suppress side reactions, the 1-butene feed stream is diluted with steam in the ratio of 10 moles of steam per mole of 1-butene. The reaction is carried out isothermally at 525°C, and at this temperature 33% of the 1-butene is converted to 1,3-butadiene. How much heat is transferred to or from the reactor per mole of entering 1-butene?
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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