A mixture of isobutylene ((CH.).CCH2, 0.400 bar partial pressure) and HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant K for the gas-phase thermal decomposition of tert-butyl chloride ((CH.).CCI) is 3.45 at 500.0 K.
A mixture of isobutylene ((CH.).CCH2, 0.400 bar partial pressure) and HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant K for the gas-phase thermal decomposition of tert-butyl chloride ((CH.).CCI) is 3.45 at 500.0 K.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:A mixture of isobutylene ((CH.):CCH2, 0.400 bar partial pressure) and
HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium
constant K for the gas-phase thermal decomposition of tert-butyl chloride
((CH.).CCI) is 3.45 at 500.0 K.
(CHs).CCI(g) (CH.).CCH:(g) + HCI(g)
a) Based on the given values, fill in the ICE table to determine the partial
pressures of all reactants and products.
b) Based on your ICE table, set up the expession for K for the decomposition a
(CH.).CCI.
(CH.).CCI(g) (CHs):CCH:(g) + HCI(g)
c) What is the partial pressure of tert-butyl chloride ((CHs).CCI) at equilibrium?
d) What is the partial pressure of isobutylene ((CHs):CCH:) at equilibrium?
e) What is the partial pressure of hydrochloric acid (HCI) at equilibrium?
f Calculate the value of Kc
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