A mixture of isobutylene ((CH.).CCH2, 0.400 bar partial pressure) and HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant K for the gas-phase thermal decomposition of tert-butyl chloride ((CH.).CCI) is 3.45 at 500.0 K.

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A mixture of isobutylene ((CH.):CCH2, 0.400 bar partial pressure) and
HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium
constant K for the gas-phase thermal decomposition of tert-butyl chloride
((CH.).CCI) is 3.45 at 500.0 K.
(CHs).CCI(g) (CH.).CCH:(g) + HCI(g)
a) Based on the given values, fill in the ICE table to determine the partial
pressures of all reactants and products.
b) Based on your ICE table, set up the expession for K for the decomposition a
(CH.).CCI.
(CH.).CCI(g) (CHs):CCH:(g) + HCI(g)
c) What is the partial pressure of tert-butyl chloride ((CHs).CCI) at equilibrium?
d) What is the partial pressure of isobutylene ((CHs):CCH:) at equilibrium?
e) What is the partial pressure of hydrochloric acid (HCI) at equilibrium?
f Calculate the value of Kc
Transcribed Image Text:A mixture of isobutylene ((CH.):CCH2, 0.400 bar partial pressure) and HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant K for the gas-phase thermal decomposition of tert-butyl chloride ((CH.).CCI) is 3.45 at 500.0 K. (CHs).CCI(g) (CH.).CCH:(g) + HCI(g) a) Based on the given values, fill in the ICE table to determine the partial pressures of all reactants and products. b) Based on your ICE table, set up the expession for K for the decomposition a (CH.).CCI. (CH.).CCI(g) (CHs):CCH:(g) + HCI(g) c) What is the partial pressure of tert-butyl chloride ((CHs).CCI) at equilibrium? d) What is the partial pressure of isobutylene ((CHs):CCH:) at equilibrium? e) What is the partial pressure of hydrochloric acid (HCI) at equilibrium? f Calculate the value of Kc
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