A galvanic cell is constructed at 25°C by connecting two half-cells; an aluminium electrode in 1.0 M aluminium nitrate, Al(NO3)3 and a lead electrode in 1.0 M lead(II) nitrate, Pb(NO3)2 using external wire and a potassium nitrate, KNO3 salt bridge. (a) Draw and label the cell diagram. (b) State the function of a salt bridge. (c) Write reaction at the anode and the cathode and the overall cell reaction. (d) Calculat

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A galvanic cell is constructed at 25°C by connecting two half-cells; an aluminium electrode in
1.0 M aluminium nitrate, Al(NO3)3 and a lead electrode in 1.0 M lead(II) nitrate, Pb(NO3)2 using
external wire and a potassium nitrate, KNO3 salt bridge.
1.
(a)
Draw and label the cell diagram.
(b)
State the function of a salt bridge.
(c)
Write reaction at the anode and the cathode and the overall cell reaction.
(d)
Calculate the standard cell potential, E°cell-
(e)
Which electrode will increase in weight? Explain your answer.
Calculate the cell potential, Ecell if the concentration of aluminium nitrate and lead(II)
nitrate are 0.50 M and 3.00 M respectively.
(f)
(g)
What would happen to the value of cell potential if:
i.
the concentration of aluminium nitrate solution is increased?
i.
the concentration of lead(II) nitrate solution is increased?
iii.
the diameter of lead electrode is decreased?
Transcribed Image Text:A galvanic cell is constructed at 25°C by connecting two half-cells; an aluminium electrode in 1.0 M aluminium nitrate, Al(NO3)3 and a lead electrode in 1.0 M lead(II) nitrate, Pb(NO3)2 using external wire and a potassium nitrate, KNO3 salt bridge. 1. (a) Draw and label the cell diagram. (b) State the function of a salt bridge. (c) Write reaction at the anode and the cathode and the overall cell reaction. (d) Calculate the standard cell potential, E°cell- (e) Which electrode will increase in weight? Explain your answer. Calculate the cell potential, Ecell if the concentration of aluminium nitrate and lead(II) nitrate are 0.50 M and 3.00 M respectively. (f) (g) What would happen to the value of cell potential if: i. the concentration of aluminium nitrate solution is increased? i. the concentration of lead(II) nitrate solution is increased? iii. the diameter of lead electrode is decreased?
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