(а) fo (b) (с) N EN : :N H

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter3: Atomic Shells And Classical Models Of Chemical Bonding
Section: Chapter Questions
Problem 58P: Draw Lewis diagrams for the following ions. In the formula the symbol of the central atom is given...
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Three possibly correct resonance forms of [NO2NH]- (connectivity is correct in all cases) are shown below.  Pick the best answer.

The image displays three resonance structures of the nitramide molecule, showcasing how electrons can be redistributed among the atoms. Each structure is labeled as (a), (b), and (c), and demonstrates different electron configurations and bond formations among nitrogen, oxygen, and hydrogen atoms.

**Structure (a):**
- The nitrogen is double-bonded to one oxygen atom, which holds a negative charge.
- The nitrogen is single-bonded to another oxygen, which is connected by a double bond to a second nitrogen.
- The second nitrogen atom has a coordinate bond with oxygen and bears a positive charge, while the oxygen bears a negative charge.
- The lone pairs on the oxygen atoms are indicated, and the second nitrogen atom is single-bonded to a hydrogen atom.

**Structure (b):**
- The nitrogen forms a single bond with an oxygen atom, which is connected to another nitrogen by a single bond.
- This configuration allows for a lone pair on the oxygen, which carries a negative charge.
- Conversely, the nitrogen connected directly to two oxygens carries a positive charge due to sharing a multiple-bond configuration with one oxygen.
- A hydrogen is bonded to a second nitrogen, which displays a lone pair.

**Structure (c):**
- Features a triple bond between two nitrogen atoms.
- The nitrogen attached to both oxygens carries a positive charge, while the oxygen connected by a single bond carries a negative charge.
- A hydrogen atom is directly bonded to the triple-bonded nitrogen.

These resonance structures illustrate the flexibility of electron placement in nitramide, helping to stabilize the molecule through varying bond orders and charge distributions.
Transcribed Image Text:The image displays three resonance structures of the nitramide molecule, showcasing how electrons can be redistributed among the atoms. Each structure is labeled as (a), (b), and (c), and demonstrates different electron configurations and bond formations among nitrogen, oxygen, and hydrogen atoms. **Structure (a):** - The nitrogen is double-bonded to one oxygen atom, which holds a negative charge. - The nitrogen is single-bonded to another oxygen, which is connected by a double bond to a second nitrogen. - The second nitrogen atom has a coordinate bond with oxygen and bears a positive charge, while the oxygen bears a negative charge. - The lone pairs on the oxygen atoms are indicated, and the second nitrogen atom is single-bonded to a hydrogen atom. **Structure (b):** - The nitrogen forms a single bond with an oxygen atom, which is connected to another nitrogen by a single bond. - This configuration allows for a lone pair on the oxygen, which carries a negative charge. - Conversely, the nitrogen connected directly to two oxygens carries a positive charge due to sharing a multiple-bond configuration with one oxygen. - A hydrogen is bonded to a second nitrogen, which displays a lone pair. **Structure (c):** - Features a triple bond between two nitrogen atoms. - The nitrogen attached to both oxygens carries a positive charge, while the oxygen connected by a single bond carries a negative charge. - A hydrogen atom is directly bonded to the triple-bonded nitrogen. These resonance structures illustrate the flexibility of electron placement in nitramide, helping to stabilize the molecule through varying bond orders and charge distributions.
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