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a) Draw a possible structural formula based on VSEPR theory

a) Draw a possible structural formula based on VSEPR theory

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Consider the compound Si2H6 a) Draw a possible structural formula based on VSEPR theory b) Use the isotope tables to discuss (in detail) how 29Si NMR spectra can help find the correct structure for the compound.
Transcribed Image Text:Consider the compound Si2H6 a) Draw a possible structural formula based on VSEPR theory b) Use the isotope tables to discuss (in detail) how 29Si NMR spectra can help find the correct structure for the compound.
119Sn 82 Nuclear Magnet. Table 4.1 NMR properties of some selected nuclei. Magnetogyric ratio/10 rad T's Quadrupole moment/10-28 m? Isotope Spin Natural Relative receptivity DC (relative to 13C) abundance (%) 5.68 x 10 8.21 x 10-3 3.58 1.54 x 10 1/2 99.985 26.7510 2H Li "Li "Be 1ºB 2.73 x 10-3 -8.0 x 10-4 -4.5 x 10-2 5.2 x 10-2 7.4 x 10-2 3.55 x 10-2 1 0.015 4.1064 1 7.42 3.9366 10.396 -3.7954 2.8748 3/2 92.58 100.0 19.58 80.42 3/2 78.8 22.1 7.54 x 10? 3/2 8.5827 13C 14N 15N 170 19F 27 AI 29 Si 31p 335 47 Ti 6.7263 1.9324 1/2 1.108 99.63 0.37 0.037 1 1.6 x 10-2 5.69 2.19 x 10-2 6.11 x 10-2 4.73 x 103 1.17 x 103 1/2 5/2 -2.7107 -3.6266 -2.6 x 10-2 3.0266 25.181 6.9706 100.0 100.0 4.70 100.0 1/2 5/2 0.149 -5.3141 10.829 2.0517 -0.9313 1/2 1/2 2.09 3.77 x 10? 9.73 x 10-2 3/2 5/2 0.76 -6.4 x 10-2 7.28 0.29 0.864 2.16 x 10 0.490 9.94 x 102 4.19 x 10-3 1.57 x 103 3.65 x 10? 0.665 3.19 x 102 99.76 9.55 100,0 2.19 7/2 3/2 7.032 -1.5120 0.3 0.03 53Cr 55 Mn 57 Fe 59 Co 63 Cu 67 Zn 7' Ga 73 Ge 75 As 17se 89 Y 95 Mo 5/2 6.598 0.55 0.8644 6.3171 1/2 7/2 100,0 0.40 7.0904 1.6726 8.1578 3/2 69.09 4.11 39.6 7.76 100.0 -0.16 0.15 0.112 5/2 3/2 -0.9332 4.5816 9/2 -0.2 0.3 0.617 1.43 x 10? 2.98 3/2 1/2 7,58 5.101 1/2 5/2. 100.0 -1.3106 0.668 2.88 15.72 1.743 0.12 1/2 100.0 -0.8420 0.177 12 51.82 -1.0828 O 197 10 Ag 1/2 48.18 -1.2449 0.276 1/2 1/2 1/2 -5.6720 -5.9330 12.75 6.97 113 Cd 12.26 7.59 117Sn -9.5301 -9.9707 7.61 19.8 1/2 5/2 8,58 25.2 5.20 x 10? 5.30 x 10? 121 Sh 1271 123 Te 125 Te 129 Xe 131 Xe 169Tm 171 Yb 183 W 187 Os 195 Pt 197 Au 57.25 100.0 6.4016 0.4010 5.3521 -0.5 -0.69 5/2 -7.011 -8.453 -7.3995 2.1935 -2.21 1/2 0.87 0.903 1/2 6.99 12.5 26.44 21.18 318 221 3.31 1/2 3/2 -0.12 1/2 1/2 100.0 3.21 4.7117 1.1131 0.6161 5.7505 14.31 4.44 5.89 x 10-2 1.14 x 10-3 14.40 1/2 1.64 1/2 33.8 19.1 3/2 100.0 0.4625 0.59 2.6 x 10-5 199 Hg 205 TI 207 Pb 209 Bi 4.7690 15.438 1/2 16.84 5.42 7.69 x 10? 70.50 22.6 100.0 1/2 1/2 5.5968 11.8 9/2 4.2988 -0.4 7.77 x 102
Transcribed Image Text:119Sn 82 Nuclear Magnet. Table 4.1 NMR properties of some selected nuclei. Magnetogyric ratio/10 rad T's Quadrupole moment/10-28 m? Isotope Spin Natural Relative receptivity DC (relative to 13C) abundance (%) 5.68 x 10 8.21 x 10-3 3.58 1.54 x 10 1/2 99.985 26.7510 2H Li "Li "Be 1ºB 2.73 x 10-3 -8.0 x 10-4 -4.5 x 10-2 5.2 x 10-2 7.4 x 10-2 3.55 x 10-2 1 0.015 4.1064 1 7.42 3.9366 10.396 -3.7954 2.8748 3/2 92.58 100.0 19.58 80.42 3/2 78.8 22.1 7.54 x 10? 3/2 8.5827 13C 14N 15N 170 19F 27 AI 29 Si 31p 335 47 Ti 6.7263 1.9324 1/2 1.108 99.63 0.37 0.037 1 1.6 x 10-2 5.69 2.19 x 10-2 6.11 x 10-2 4.73 x 103 1.17 x 103 1/2 5/2 -2.7107 -3.6266 -2.6 x 10-2 3.0266 25.181 6.9706 100.0 100.0 4.70 100.0 1/2 5/2 0.149 -5.3141 10.829 2.0517 -0.9313 1/2 1/2 2.09 3.77 x 10? 9.73 x 10-2 3/2 5/2 0.76 -6.4 x 10-2 7.28 0.29 0.864 2.16 x 10 0.490 9.94 x 102 4.19 x 10-3 1.57 x 103 3.65 x 10? 0.665 3.19 x 102 99.76 9.55 100,0 2.19 7/2 3/2 7.032 -1.5120 0.3 0.03 53Cr 55 Mn 57 Fe 59 Co 63 Cu 67 Zn 7' Ga 73 Ge 75 As 17se 89 Y 95 Mo 5/2 6.598 0.55 0.8644 6.3171 1/2 7/2 100,0 0.40 7.0904 1.6726 8.1578 3/2 69.09 4.11 39.6 7.76 100.0 -0.16 0.15 0.112 5/2 3/2 -0.9332 4.5816 9/2 -0.2 0.3 0.617 1.43 x 10? 2.98 3/2 1/2 7,58 5.101 1/2 5/2. 100.0 -1.3106 0.668 2.88 15.72 1.743 0.12 1/2 100.0 -0.8420 0.177 12 51.82 -1.0828 O 197 10 Ag 1/2 48.18 -1.2449 0.276 1/2 1/2 1/2 -5.6720 -5.9330 12.75 6.97 113 Cd 12.26 7.59 117Sn -9.5301 -9.9707 7.61 19.8 1/2 5/2 8,58 25.2 5.20 x 10? 5.30 x 10? 121 Sh 1271 123 Te 125 Te 129 Xe 131 Xe 169Tm 171 Yb 183 W 187 Os 195 Pt 197 Au 57.25 100.0 6.4016 0.4010 5.3521 -0.5 -0.69 5/2 -7.011 -8.453 -7.3995 2.1935 -2.21 1/2 0.87 0.903 1/2 6.99 12.5 26.44 21.18 318 221 3.31 1/2 3/2 -0.12 1/2 1/2 100.0 3.21 4.7117 1.1131 0.6161 5.7505 14.31 4.44 5.89 x 10-2 1.14 x 10-3 14.40 1/2 1.64 1/2 33.8 19.1 3/2 100.0 0.4625 0.59 2.6 x 10-5 199 Hg 205 TI 207 Pb 209 Bi 4.7690 15.438 1/2 16.84 5.42 7.69 x 10? 70.50 22.6 100.0 1/2 1/2 5.5968 11.8 9/2 4.2988 -0.4 7.77 x 102
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