A dimerization 2A > A2 is found to be first order with a half life of 666 s. This somewhat surprising result is explained by postulating the following 8. mechanism A* +A- → A, k → A* Where k2 >>kı (a) What is the value for the rate constant k1? (b) if the initial concentration of A is 0.05 M, how much time is required to reach [A] =0.0125 M?
A dimerization 2A > A2 is found to be first order with a half life of 666 s. This somewhat surprising result is explained by postulating the following 8. mechanism A* +A- → A, k → A* Where k2 >>kı (a) What is the value for the rate constant k1? (b) if the initial concentration of A is 0.05 M, how much time is required to reach [A] =0.0125 M?
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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![A dimerization 2A > A2 is found to be first order with a half life of 666
s. This somewhat surprising result is explained by postulating the following
8.
mechanism
A* +A- → A,
k
→ A*
Where k2 >>kı (a) What is the value for the rate constant k1? (b) if the initial
concentration of A is 0.05 M, how much time is required to reach [A] =0.0125
M?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F982ffa95-a5fa-41c5-8f7b-68fa04dc5bea%2F2d5a32d1-a3cf-42ee-8bd6-b919b01d9a0f%2F4376xsd_processed.png&w=3840&q=75)
Transcribed Image Text:A dimerization 2A > A2 is found to be first order with a half life of 666
s. This somewhat surprising result is explained by postulating the following
8.
mechanism
A* +A- → A,
k
→ A*
Where k2 >>kı (a) What is the value for the rate constant k1? (b) if the initial
concentration of A is 0.05 M, how much time is required to reach [A] =0.0125
M?
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