A continuous fractionating column is required to separate a mixture containing 0.40 mol fraction n-heptane (MW= 100) and 0.60 mol fraction n-octane (MW = 114) into overhead products of 99 mol% heptane and bottom products of 1 mol% heptane. The column is to operate at a pressure (at top) of 101.3 kN/m² with a pressure drop across the tower of 25 kPa. The feed is a saturated mixture with 30% vapor, and is supplied to the column at 0.070 kmol/s. The reflux ratio (L/D) is 2.5 and the fraction of the cross-sectional area available for vapor flow is 0.88. If the vapor velocity is 0.8 m/s, determine the required diameter on stripping section based on the conditions at the bottom of the tower, where you can use pure n-octane for the evaluation of vapor density. Vapor pressure for n-octane In P*(kPa) = 14.2368 - 3304.16/(T(K) - 55.2278) Gas constant R = 8314 J/kmol K. Hint: First find the pressure at the bottom of the column, then determine the temperature using the vapor pressure equation

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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A continuous fractionating column is required to separate a mixture containing 0.40 mol fraction
n-heptane (MW= 100) and 0.60 mol fraction n-octane (MW = 114) into overhead products of 99
mol% heptane and bottom products of 1 mol% heptane. The column is to operate at a pressure
(at top) of 101.3 kN/m² with a pressure drop across the tower of 25 kPa. The feed is a saturated
mixture with 30% vapor, and is supplied to the column at 0.070 kmol/s. The reflux ratio (L/D) is
2.5 and the fraction of the cross-sectional area available for vapor flow is 0.88. If the vapor
velocity is 0.8 m/s, determine the required diameter on stripping section based on the conditions
at the bottom of the tower, where you can use pure n-octane for the evaluation of vapor density.
Vapor pressure for n-octane
In P*(kPa) = 14.2368 - 3304.16/(T(K) - 55.2278)
Gas constant R = 8314 J/kmol K.
Hint: First find the pressure at the bottom of the column, then determine the temperature using
the vapor pressure equation.
Transcribed Image Text:A continuous fractionating column is required to separate a mixture containing 0.40 mol fraction n-heptane (MW= 100) and 0.60 mol fraction n-octane (MW = 114) into overhead products of 99 mol% heptane and bottom products of 1 mol% heptane. The column is to operate at a pressure (at top) of 101.3 kN/m² with a pressure drop across the tower of 25 kPa. The feed is a saturated mixture with 30% vapor, and is supplied to the column at 0.070 kmol/s. The reflux ratio (L/D) is 2.5 and the fraction of the cross-sectional area available for vapor flow is 0.88. If the vapor velocity is 0.8 m/s, determine the required diameter on stripping section based on the conditions at the bottom of the tower, where you can use pure n-octane for the evaluation of vapor density. Vapor pressure for n-octane In P*(kPa) = 14.2368 - 3304.16/(T(K) - 55.2278) Gas constant R = 8314 J/kmol K. Hint: First find the pressure at the bottom of the column, then determine the temperature using the vapor pressure equation.
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