a) Consider the cell, Zn(s)|ZnCl₂ (0.0050 mol kg¯¹)|Hg₂Cl₂(s)|Hg(1), for which the cell reaction is Hg₂Cl₂(s) + Zn(s)→→2 Hg(1) + 2 Cl−(aq) + Zn²+ (aq). Given that E° (Zn²*,Zn) = −0.7628 V, E° (Hg2Cl2,Hg) = +0.2676 V, and that the cell potential is +1.2272 V. (n=2) i. ii. iii. Write the Nernst equation for the cell. Determine the standard cell potential Determine reaction Gibbs energy, ArG and A.GⓇ
a) Consider the cell, Zn(s)|ZnCl₂ (0.0050 mol kg¯¹)|Hg₂Cl₂(s)|Hg(1), for which the cell reaction is Hg₂Cl₂(s) + Zn(s)→→2 Hg(1) + 2 Cl−(aq) + Zn²+ (aq). Given that E° (Zn²*,Zn) = −0.7628 V, E° (Hg2Cl2,Hg) = +0.2676 V, and that the cell potential is +1.2272 V. (n=2) i. ii. iii. Write the Nernst equation for the cell. Determine the standard cell potential Determine reaction Gibbs energy, ArG and A.GⓇ
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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![Question 3
a) Consider the cell, Zn(s)|ZnCl₂ (0.0050 mol kg ¹) Hg₂Cl₂(s)|Hg(1), for which the cell
reaction is Hg₂Cl₂(s) + Zn(s)→→2 Hg(1) + 2 Cl−(aq) + Zn²+ (aq).
Given that E° (Zn²+, Zn) = -0.7628 V, E° (Hg₂Cl₂,Hg) = +0.2676 V, and that the cell potential
is +1.2272 V. (n=2)
i.
ii.
Write the Nernst equation for the cell.
iii.
Determine the standard cell potential
|
13:52
Determine reaction Gibbs energy, ArG and A.GⓇ
iv. Suggest a physical interpretation of the dependence of the Gibbs energy on the tem](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4cb71868-6f58-4dcf-8038-c59a628909aa%2F85e9d38d-3aff-42e9-ac54-f6e77e27f177%2Fuatpujp_processed.png&w=3840&q=75)
Transcribed Image Text:Question 3
a) Consider the cell, Zn(s)|ZnCl₂ (0.0050 mol kg ¹) Hg₂Cl₂(s)|Hg(1), for which the cell
reaction is Hg₂Cl₂(s) + Zn(s)→→2 Hg(1) + 2 Cl−(aq) + Zn²+ (aq).
Given that E° (Zn²+, Zn) = -0.7628 V, E° (Hg₂Cl₂,Hg) = +0.2676 V, and that the cell potential
is +1.2272 V. (n=2)
i.
ii.
Write the Nernst equation for the cell.
iii.
Determine the standard cell potential
|
13:52
Determine reaction Gibbs energy, ArG and A.GⓇ
iv. Suggest a physical interpretation of the dependence of the Gibbs energy on the tem
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