O + 88www-awn.aleks.comFilesStigma project - Google DocsFilesb Answered: A chemist carefully measure...X ALEKS - Kayla Scoblick - LearnTHERMOCHEMISTRYКaylaCalculating specific heat capacityA chemist carefully measures the amount of heat needed to raise the temperature of a 0.46 kg sample of a pure substance from 19.9 °C to 38.8 °C. Theexperiment shows that 16. kJ of heat are needed. What can the chemist report for the specific heat capacity of the substance? Be sure your answer has thecorrect number of significant digits.- 1- 1•Kx10ArExplanationCheckO 2021 McGraw Hill LLC. All Rights Reserved.Terms of Use | Privacy Center | Accessibility

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Answered: A chemist carefully measures the amount…

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter9: Energy And Chemistry

Section: Chapter Questions

Problem 9.101PAE

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9.100 Two baking sheets are made of different metals. You purchase both and bake a dozen cookies on each sheet at the same time in your oven. You observe that after 9 minutes, the cookies on one sheet are slightly burned on the bottom, whereas those on the other sheet are fine. (You are curious and you vary the conditions so you know the result is not caused by the oven.) (a) How can you use this observation to infer something about the specific heat of the materials in the baking sheets? (b) What is themathematical reasoning (equation) that you need to support your conclusion?
What is the heat gained/released at constant pressure equal1o (qp = ?)? What is the heat gained/released at constant volume equal to (qv = ?)? Explain why H is obtained directly from a coffee-cup calorimeter, whereas E is obtained directly from a bomb calorimeter.
The statement Energycan beneithercreatednor destroyedis sometimes used as an equivalent statement of the first law of thermodynamics. There areinaccuracies to the statement, however. Restate it tomake it less inaccurate.
When 1.000 g of ethylene glycol, C2H6O2, is burned at 25C and 1.00 atmosphere pressure, H2O(l) and CO2(g) are formed with the evolution of 19.18 kJ of heat. a Calculate the molar enthalpy of formation of ethylene glycol. (It will be necessary to use data from Appendix C.) b Gf of ethylene glycol is 322.5 kJ/mol. What is G for the combustion of 1 mol ethylene glycol? c What is S for the combustion of 1 mol ethylene glycol?
Consider the reaction 2HCl(aq)+Ba(OH)2(aq)BaCl2(aq)+2H2O(l)H=118KJ Calculate the heat when 100.0 rnL of 0.500 M HCl is mixed with 300.0 mL of 0.100 M Ba(OH)2 Assuming that the temperature of both solutions was initially 25.0C and that the final mixture has a mass of 400.0 g and a specific heat capacity of 4.18 J/C g, calculate the final temperature of the mixture.
9.42 Why is enthalpy generally more useful than internal energy in the thermodynamics of real world systems?
Nitric acid, HNO3, can be prepared by the following sequence of reactions: 4NH3(g)+5O2(g)4NO(g)+6H2O(g)2NO(g)+O2(g)2NO2(g)3NO2(g)+H2O(l)2HNO3(l)+NO(g) How much heat is evolved when 1 mol of NH3(g) is converted to HNO3(l)? Assume standard states at 25 C.
Would the amount of heat absorbed by the dissolution in Example 5.6 appear greater, lesser, or remain the same if the heat capacity of the calorimeter were taken into account? Explain your answer.
Aballoon filled with 0.505 mole of gascontracts reversibly from 1.0L to 0.10 L ata constant temperature of 5.0C. In doing so, it loses 2690J of heat. Calculate w, q, U, and H for the process.
9.50 When a 13.0-g sample of NaOH(s) dissolves in 400.0 mL of water in a coffee cup calorimeter, the temperature of the water changes from 22.6°C to 30.7C Assuming that the specific heat capacity of the solution is the same as for water, calculate (a) the heat transfer from system to surroundings and (b) H for the reaction NaOH(s)Na+(aq)+OH(aq)
10.101 Fluorine reacts with liquid water to form gaseous hydrogen fluoride and oxygen. (a) Write a balanced chemical equation for this reaction. (b) Use tabulated data to determine the free energy change for the reaction and comment on its spontaneity. (c) Use tabulated data to calculate the enthalpy change of the reaction. (d) Determine how much heat flows and in what direction when 34.5 g of fluorine gas is bubbled through excess water.
In earlier times, ethyl ether was commonly used as an anesthetic. It is, however, highly flammable. When five milliliters of ethyl ether, C4H10O(l)(d=0.714g/mL), are burned in a bomb calorimeter, the temperature rises from 23.5C to 39.7C. The calorimeter contains 1.200 kg of water and has a heat capacity of 5.32 kJ/C. (a) What is qH2o? (b) What is qcal? (c) What is q for the combustion of 5.00 mL of ethyl ether? (d) What is q for the combustion of one mole of ethyl ether?

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