A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 70.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 4PF, (g) + 10H₂(g) → P4 (s) + 20HF (g) ΔΗ = 1005. kJ J K AS = 2929. AG = [] kJ Which is spontaneous? this reaction the reverse reaction neither S

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A chemical engineer is studying the two reactions shown in the table below.

In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 70.0 °C and constant total pressure. Then, she measures the reaction enthalpy ΔH and reaction entropy ΔS of the first reaction, and the reaction enthalpy ΔH and reaction free energy ΔG of the second reaction. The results of her measurements are shown in the table.

Complete the table. That is, calculate ΔG for the first reaction and ΔS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium.

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Reaction equation:
\[ 4PF_5(g) + 10H_2(g) \rightarrow P_4(s) + 20HF(g) \]

Table:

- ΔH = 1005. kJ
- ΔS = 2929. J/K
- ΔG = [ ] kJ

Which is spontaneous?
- [ ] this reaction
- [ ] the reverse reaction
- [ ] neither

---

Note: There is a graphic user interface illustration depicting `Figure` handling in design software, including icons for arrangement options (e.g., changing layout or stacking).
Transcribed Image Text:A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 70.0 °C and constant total pressure. Then, she measures the reaction enthalpy ΔH and reaction entropy ΔS of the first reaction, and the reaction enthalpy ΔH and reaction free energy ΔG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate ΔG for the first reaction and ΔS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. --- Reaction equation: \[ 4PF_5(g) + 10H_2(g) \rightarrow P_4(s) + 20HF(g) \] Table: - ΔH = 1005. kJ - ΔS = 2929. J/K - ΔG = [ ] kJ Which is spontaneous? - [ ] this reaction - [ ] the reverse reaction - [ ] neither --- Note: There is a graphic user interface illustration depicting `Figure` handling in design software, including icons for arrangement options (e.g., changing layout or stacking).
### Chemical Reaction and Thermodynamics

**Chemical Reaction:**
\[ \text{N}_2\text{H}_4 (g) + \text{H}_2 (g) \rightarrow 2\text{NH}_3 (g) \]

**Thermodynamic Data:**

- **Change in Enthalpy (\(\Delta H\)):** \(-188 \, \text{kJ}\)

- **Change in Entropy (\(\Delta S\)):** A value is missing (\(\Box \, \text{J/K}\))

- **Change in Gibbs Free Energy (\(\Delta G\)):** \(-16 \, \text{kJ}\)

**Spontaneity of Reaction:**

The image poses a question: "Which is spontaneous?"

Options include:
- This reaction
- The reverse reaction
- Neither

Understanding these thermodynamic terms:
- \(\Delta H\) (Enthalpy Change): Indicates heat absorbed or released.
- \(\Delta S\) (Entropy Change): Measures the disorder or randomness.
- \(\Delta G\) (Gibbs Free Energy Change): Determines reaction spontaneity. Negative \(\Delta G\) suggests a spontaneous process under constant temperature and pressure.

Further exploration could involve calculating the missing \(\Delta S\) or discussing factors affecting spontaneity.
Transcribed Image Text:### Chemical Reaction and Thermodynamics **Chemical Reaction:** \[ \text{N}_2\text{H}_4 (g) + \text{H}_2 (g) \rightarrow 2\text{NH}_3 (g) \] **Thermodynamic Data:** - **Change in Enthalpy (\(\Delta H\)):** \(-188 \, \text{kJ}\) - **Change in Entropy (\(\Delta S\)):** A value is missing (\(\Box \, \text{J/K}\)) - **Change in Gibbs Free Energy (\(\Delta G\)):** \(-16 \, \text{kJ}\) **Spontaneity of Reaction:** The image poses a question: "Which is spontaneous?" Options include: - This reaction - The reverse reaction - Neither Understanding these thermodynamic terms: - \(\Delta H\) (Enthalpy Change): Indicates heat absorbed or released. - \(\Delta S\) (Entropy Change): Measures the disorder or randomness. - \(\Delta G\) (Gibbs Free Energy Change): Determines reaction spontaneity. Negative \(\Delta G\) suggests a spontaneous process under constant temperature and pressure. Further exploration could involve calculating the missing \(\Delta S\) or discussing factors affecting spontaneity.
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