A chemical engineer is studying the following reaction: H₂(9) + I₂(g) →2 HI(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.93. The engineer charges ("fills") three reaction vessels with hydrogen and iodine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel B с compound H₂ 1₂ HI H₂ 1₂ HI H₂ 1₂ HI pressure 2.59 atm 4.68 atm 4.19 atm 2.87 atm 4.96 atm 3.63 atm 3.72 atm 6.43 atm 4.71 atm expected change in pressure O↓ decrease O↓ decrease O↓ decrease O↓ decrease O ↓ decrease ↓decrease ↓ decrease O↓ decrease O↓ decrease ↑ increase ↑ increase increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase increase X (no change) (no change) O (no change) (no change) O (no change) (no change) O (no change) (no change) (no change)
A chemical engineer is studying the following reaction: H₂(9) + I₂(g) →2 HI(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.93. The engineer charges ("fills") three reaction vessels with hydrogen and iodine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel B с compound H₂ 1₂ HI H₂ 1₂ HI H₂ 1₂ HI pressure 2.59 atm 4.68 atm 4.19 atm 2.87 atm 4.96 atm 3.63 atm 3.72 atm 6.43 atm 4.71 atm expected change in pressure O↓ decrease O↓ decrease O↓ decrease O↓ decrease O ↓ decrease ↓decrease ↓ decrease O↓ decrease O↓ decrease ↑ increase ↑ increase increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase increase X (no change) (no change) O (no change) (no change) O (no change) (no change) O (no change) (no change) (no change)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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KINETICS AND EQUILIBRIUM
Using an equilibrium constant to predict the direction of...
A chemical engineer is studying the following reaction:
H₂(g) +1₂(g) → 2 HI(g)
At the temperature the engineer picks, the equilibrium constant K for this reaction is 0.93.
The engineer charges ("fills") three reaction vessels with hydrogen and iodine, and lets the reaction begin. He then measures the composition of the mixture
inside each vessel from time to time. His first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time he measures the compositions.
reaction
vessel
A
B
C
compound
H₂
1₂
HI
H₂
1₂
HI
H₂
1₂
HI
pressure
2.59 atm
4.68 atm
4.19 atm
2.87 atm
4.96 atm
3.63 atm
3.72 atm
6.43 atm
4.71 atm
expected change in pressure
O↓ decrease
* increase
↑ increase
↑ increase
↑ increase
increase
increase
* increase
↑ increase
increase
↓ decrease
↓ decrease
↓ decrease
↓ decrease
O ↓ decrease
O↓ decrease
↓ decrease
↓ decrease
X
O (no change)
O (no change)
(no change)
O (no change)
(no change)
O (no change)
O (no change)
(no change)
(no change)
3/5
Ś"
Transcribed Image Text:=
KINETICS AND EQUILIBRIUM
Using an equilibrium constant to predict the direction of...
A chemical engineer is studying the following reaction:
H₂(g) +1₂(g) → 2 HI(g)
At the temperature the engineer picks, the equilibrium constant K for this reaction is 0.93.
The engineer charges ("fills") three reaction vessels with hydrogen and iodine, and lets the reaction begin. He then measures the composition of the mixture
inside each vessel from time to time. His first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time he measures the compositions.
reaction
vessel
A
B
C
compound
H₂
1₂
HI
H₂
1₂
HI
H₂
1₂
HI
pressure
2.59 atm
4.68 atm
4.19 atm
2.87 atm
4.96 atm
3.63 atm
3.72 atm
6.43 atm
4.71 atm
expected change in pressure
O↓ decrease
* increase
↑ increase
↑ increase
↑ increase
increase
increase
* increase
↑ increase
increase
↓ decrease
↓ decrease
↓ decrease
↓ decrease
O ↓ decrease
O↓ decrease
↓ decrease
↓ decrease
X
O (no change)
O (no change)
(no change)
O (no change)
(no change)
O (no change)
O (no change)
(no change)
(no change)
3/5
Ś
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