A cation vacancy paired with an anion vacancy is called Schottky defect. The Frenkel defect is an ion vacancy and a corresponding jon interstitial impurity. Other types of

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%

Please help

A cation vacancy paired with an anion vacancy is called
Schottky defect. The Frenkel defect is an ion vacancy and a
corresponding ion interstitial impurity. Other types of
defects can exist. One particular type involves multiple
oxidation states. Transiton metal atoms, such as iron, can
Fe
have more than one oxidation state or charge. For example
iron can exist as Fe*, Fe2+, or Fe3+. If the oxidation state of an
Fe
Fe
ion in a crystal changes, that is another type of defect. The
figure below shows a crystal of FeO after one of these defects
is formed. One of the iron atoms has been oxidized to a
charge of +3 instead of the normal +2. You will use charge
balance to determine the defects that form when the
oxidation state of one atom is changed. Keeping this in mind
answer the following with respect to the figure below:
11. What is the charge on the crystal before the defect is formed.
12. What is the charge on the crystal after the defect is formed.
13. What is one thing you could do to the crystal to try to make the charge zero? What is the
charge after you do this?
The charge may not be zero at this point; you should just do one thing that starts to get
you in the right direction.
14. What is the unit cell of ferrite?
15. Describe the unit cell of austenite.
16. What change has occurred on going from the austenite form to the martensite form?
Transcribed Image Text:A cation vacancy paired with an anion vacancy is called Schottky defect. The Frenkel defect is an ion vacancy and a corresponding ion interstitial impurity. Other types of defects can exist. One particular type involves multiple oxidation states. Transiton metal atoms, such as iron, can Fe have more than one oxidation state or charge. For example iron can exist as Fe*, Fe2+, or Fe3+. If the oxidation state of an Fe Fe ion in a crystal changes, that is another type of defect. The figure below shows a crystal of FeO after one of these defects is formed. One of the iron atoms has been oxidized to a charge of +3 instead of the normal +2. You will use charge balance to determine the defects that form when the oxidation state of one atom is changed. Keeping this in mind answer the following with respect to the figure below: 11. What is the charge on the crystal before the defect is formed. 12. What is the charge on the crystal after the defect is formed. 13. What is one thing you could do to the crystal to try to make the charge zero? What is the charge after you do this? The charge may not be zero at this point; you should just do one thing that starts to get you in the right direction. 14. What is the unit cell of ferrite? 15. Describe the unit cell of austenite. 16. What change has occurred on going from the austenite form to the martensite form?
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Growth and Structure of Solid Surfaces
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY