A calorimeter contains 18.0 mL of water at 14.0 °C. When 1.30 g of X (a substance with a molar mass of 74.0 g/mol ) is added, it dissolves via the reaction X(s) + H,O(1)→X(aq) and the temperature of the solution increases to 29.0 °C. Calculate the enthalpy change, AH¸ for this reaction per mole of X. Assume that the specific heat of the resulting solution is equal to that of water [4.18 J/(g .°C)], that density of water is 1.00 g/mL, and that no heat is lost to the calorimeter itself, nor to the surroundings.

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A calorimeter contains 18.0 mL of water at 14.0 °C. When 1.30 g of X (a substance with a molar mass of 74.0 g/mol ) is added, it dissolves
via the reaction
X(s) + H,O(1)→X(aq)
and the temperature of the solution increases to 29.0 °C
Calculate the enthalpy change, AH, for this reaction per mole of X.
Assume that the specific heat of the resulting solution is equal to that of water [4.18 J/(g - C)], that density of water is 1.00 g/mL, and that no
heat is lost to the calorimeter itself, nor to the surroundings.
Express the change in enthalpy in kilojoules per mole to three significant figures.
Transcribed Image Text:A calorimeter contains 18.0 mL of water at 14.0 °C. When 1.30 g of X (a substance with a molar mass of 74.0 g/mol ) is added, it dissolves via the reaction X(s) + H,O(1)→X(aq) and the temperature of the solution increases to 29.0 °C Calculate the enthalpy change, AH, for this reaction per mole of X. Assume that the specific heat of the resulting solution is equal to that of water [4.18 J/(g - C)], that density of water is 1.00 g/mL, and that no heat is lost to the calorimeter itself, nor to the surroundings. Express the change in enthalpy in kilojoules per mole to three significant figures.
A calorimeter is an insulated device in which a chemical
reaction is contained. By measuring the temperature change,
AT, we can calculate the heat released or absorbed during
the reaction using the following equation:
q= specific heat x mass × AT
Or, if the calorimeter has a predetermined heat capacity, C,
the equation becomes
q=C x AT
At constant pressure, the enthalpy change for the reaction,
AH, is equal to the heat, qp, that is,
AH= 4p
but it is usually expressed per mole of reactant and with a
sign opposite to that of q for the surroundings. The total
internal energy change, AE (sometimes referred to as
AU), is the sum of heat, q, and work done, w
AE=q+w
However, at constant volume (as with a bomb calorimeter)
W-0 and so AE= qu.
Transcribed Image Text:A calorimeter is an insulated device in which a chemical reaction is contained. By measuring the temperature change, AT, we can calculate the heat released or absorbed during the reaction using the following equation: q= specific heat x mass × AT Or, if the calorimeter has a predetermined heat capacity, C, the equation becomes q=C x AT At constant pressure, the enthalpy change for the reaction, AH, is equal to the heat, qp, that is, AH= 4p but it is usually expressed per mole of reactant and with a sign opposite to that of q for the surroundings. The total internal energy change, AE (sometimes referred to as AU), is the sum of heat, q, and work done, w AE=q+w However, at constant volume (as with a bomb calorimeter) W-0 and so AE= qu.
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